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On the catalytic efficacy of low-oxi...

Hadlington, Terrance John.

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On the catalytic efficacy of low-oxidation state group 14 complexes

紀錄類型:	書目-電子資源 : Monograph/item
正題名/作者:	On the catalytic efficacy of low-oxidation state group 14 complexes/ by Terrance John Hadlington.
作者:	Hadlington, Terrance John.
出版者:	Cham :Springer International Publishing : : 2017.,
面頁冊數:	xix, 243 p. :ill., digital ;24 cm.
內容註:	General Introduction -- The Development of Extremely Bulky Amide Ligands and their Application to the Synthesis of Group 14 Element(II) Halides -- Synthesis and Reactivity of Heavier Alkyne Analogues Stabilised by Extremely Bulky Amide Ligands -- Reactivity of Low-Coordinate Group 14 Element(II) Hydride Complexes -- Stoichiometric Reactivity and Catalytic Applications of Heavier Tetrelene Derivatives -- The Use of a Bulky Boryl-Substituted Amide Ligand in Low-Oxidation State Group 14 Element Chemistry.
Contained By:	Springer eBooks
標題:	Group 14 elements. -
電子資源:	http://dx.doi.org/10.1007/978-3-319-51807-7
ISBN:	9783319518077

On the catalytic efficacy of low-oxidation state group 14 complexes
Hadlington, Terrance John.

On the catalytic efficacy of low-oxidation state group 14 complexes[electronic resource] /by Terrance John Hadlington. - Cham :Springer International Publishing :2017. - xix, 243 p. :ill., digital ;24 cm. - Springer theses,2190-5053. - Springer theses..

General Introduction -- The Development of Extremely Bulky Amide Ligands and their Application to the Synthesis of Group 14 Element(II) Halides -- Synthesis and Reactivity of Heavier Alkyne Analogues Stabilised by Extremely Bulky Amide Ligands -- Reactivity of Low-Coordinate Group 14 Element(II) Hydride Complexes -- Stoichiometric Reactivity and Catalytic Applications of Heavier Tetrelene Derivatives -- The Use of a Bulky Boryl-Substituted Amide Ligand in Low-Oxidation State Group 14 Element Chemistry.

This outstanding thesis describes a detailed investigation into the use of low-oxidation-state group 14 complexes in catalysis, developed at the cutting edge of inorganic and organometallic chemistry. It includes the preparation of a number of landmark compounds, some of which challenge our current understanding of metal-metal bonding and low-oxidation-state main group chemistry. Among the many highlights of this thesis, the standout result is the development of the first well-defined, low- oxidation-state main group hydride systems as highly efficient catalysts in the hydroboration of carbonyl substrates, including carbon dioxide, which are as efficient as those observed in more traditional, transition-metal catalyses. These results essentially define a new subdiscipline of chemistry.

ISBN: 9783319518077

Standard No.: 10.1007/978-3-319-51807-7doiSubjects--Topical Terms:

3221274
Group 14 elements.

LC Class. No.: QD181.C1

Dewey Class. No.: 546.68

On the catalytic efficacy of low-oxidation state group 14 complexes
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520 $a This outstanding thesis describes a detailed investigation into the use of low-oxidation-state group 14 complexes in catalysis, developed at the cutting edge of inorganic and organometallic chemistry. It includes the preparation of a number of landmark compounds, some of which challenge our current understanding of metal-metal bonding and low-oxidation-state main group chemistry. Among the many highlights of this thesis, the standout result is the development of the first well-defined, low- oxidation-state main group hydride systems as highly efficient catalysts in the hydroboration of carbonyl substrates, including carbon dioxide, which are as efficient as those observed in more traditional, transition-metal catalyses. These results essentially define a new subdiscipline of chemistry.
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