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Organometallics for green catalysis

Dixneuf, Pierre H.

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Organometallics for green catalysis

紀錄類型:	書目-電子資源 : Monograph/item
正題名/作者:	Organometallics for green catalysis/ edited by Pierre H. Dixneuf, Jean-Francois Soule.
其他作者:	Dixneuf, Pierre H.
出版者:	Cham :Springer International Publishing : : 2019.,
面頁冊數:	x, 301 p. :ill., digital ;24 cm.
內容註:	Metal-Catalysed Hydrogenation of CO2 into Methanol -- Catalytic C-C Bond Formations from CO2 with Alkenes -- Recent advances on CO2 utilization as C1 building block in C-N and C-O bond formation -- "Alkene Metathesis for Transformation of Renewables" -- Metal-Catalyzed Aromatic C-O Bond Activation/Transformation -- Hydrogenation/Dehydrogenation of Unsaturated Bonds with Iron Pincer Catalysis -- Conversion of Alcohols to Carboxylates Using Water and Base with H2 Liberation -- Selective Transfer-hydrogenation of α,β-Unsaturated Carbonyl Compounds -- Functionalization of C(sp2)-H Bonds of Arenes and Heteroarenes Assisted by Photoredox-Catalysts for the C-C Bond Formation -- Green Cross-Coupling using Visible-light for C-O and C-N Bond Formation.
Contained By:	Springer eBooks
標題:	Organometallic compounds. -
電子資源:	https://doi.org/10.1007/978-3-030-10955-4
ISBN:	9783030109554

Organometallics for green catalysis
Organometallics for green catalysis[electronic resource] /edited by Pierre H. Dixneuf, Jean-Francois Soule. - Cham :Springer International Publishing :2019. - x, 301 p. :ill., digital ;24 cm. - Topics in organometallic chemistry,631436-6002 ;. - Topics in organometallic chemistry ;63..

Metal-Catalysed Hydrogenation of CO2 into Methanol -- Catalytic C-C Bond Formations from CO2 with Alkenes -- Recent advances on CO2 utilization as C1 building block in C-N and C-O bond formation -- "Alkene Metathesis for Transformation of Renewables" -- Metal-Catalyzed Aromatic C-O Bond Activation/Transformation -- Hydrogenation/Dehydrogenation of Unsaturated Bonds with Iron Pincer Catalysis -- Conversion of Alcohols to Carboxylates Using Water and Base with H2 Liberation -- Selective Transfer-hydrogenation of α,β-Unsaturated Carbonyl Compounds -- Functionalization of C(sp2)-H Bonds of Arenes and Heteroarenes Assisted by Photoredox-Catalysts for the C-C Bond Formation -- Green Cross-Coupling using Visible-light for C-O and C-N Bond Formation.

This volume presents the latest developments in the use of organometallic catalysis for the formation of bulk chemicals and the production of energy, via green processes including efficient utilization of waste feedstocks from industry. The chemistry of carbon dioxide relating to its hydrogenation into methanol -an eco-friendly energy storage strategy- and its uses as C1 synthon for the formation of important building-blocks for fine chemicals industry are covered. Catalytic hydrogenations of various functional groups and hydrogen transfer reactions including the use of first row metal catalysts are presented as well as the conversion of alcohols to carboxylates via hydrogen transfer with a zero-waste strategy using water. Transformation of renewable or bio-based raw materials is surveyed through alkene metathesis and C-O bond activations and functionalizations. A green aspect for selective formation of C-C, C-O and C-N bonds involves direct regioselective C-H bond activations and functionalizations. These transformations can now be promoted under mild reaction conditions due to the use photoredox catalyts. C-H bond oxidation using visible light leads mainly to the formation of C-O and C-N bonds, whereas cross-coupled C-C bonds can be formed through the radical additions on (hetero) arenes using photoredox assisted mechanism.

ISBN: 9783030109554

Standard No.: 10.1007/978-3-030-10955-4doiSubjects--Topical Terms:

560494
Organometallic compounds.

LC Class. No.: QD411 / .O743 2019

Dewey Class. No.: 661.895

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520 $a This volume presents the latest developments in the use of organometallic catalysis for the formation of bulk chemicals and the production of energy, via green processes including efficient utilization of waste feedstocks from industry. The chemistry of carbon dioxide relating to its hydrogenation into methanol -an eco-friendly energy storage strategy- and its uses as C1 synthon for the formation of important building-blocks for fine chemicals industry are covered. Catalytic hydrogenations of various functional groups and hydrogen transfer reactions including the use of first row metal catalysts are presented as well as the conversion of alcohols to carboxylates via hydrogen transfer with a zero-waste strategy using water. Transformation of renewable or bio-based raw materials is surveyed through alkene metathesis and C-O bond activations and functionalizations. A green aspect for selective formation of C-C, C-O and C-N bonds involves direct regioselective C-H bond activations and functionalizations. These transformations can now be promoted under mild reaction conditions due to the use photoredox catalyts. C-H bond oxidation using visible light leads mainly to the formation of C-O and C-N bonds, whereas cross-coupled C-C bonds can be formed through the radical additions on (hetero) arenes using photoredox assisted mechanism.
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