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[ subject:"Chemistry, Physical." ]
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The internal rearrangement dynamics ...
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University of California, Berkeley.
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The internal rearrangement dynamics of organometallic complexes investigated with ultrafast infrared spectroscopy.
紀錄類型:
書目-語言資料,印刷品 : Monograph/item
正題名/作者:
The internal rearrangement dynamics of organometallic complexes investigated with ultrafast infrared spectroscopy./
作者:
Glascoe, Elizabeth Anne.
面頁冊數:
196 p.
附註:
Adviser: Charles B. Harris.
Contained By:
Dissertation Abstracts International70-04B.
標題:
Chemistry, Physical. -
電子資源:
http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3353302
ISBN:
9781109099034
The internal rearrangement dynamics of organometallic complexes investigated with ultrafast infrared spectroscopy.
Glascoe, Elizabeth Anne.
The internal rearrangement dynamics of organometallic complexes investigated with ultrafast infrared spectroscopy.
- 196 p.
Adviser: Charles B. Harris.
Thesis (Ph.D.)--University of California, Berkeley, 2006.
The rearrangement dynamics of transition metal complexes are of fundamental scientific importance and also of practical industrial relevance being widely used in photo-activated synthesis. The first step after photo-activation is the stabilization of the coordinatively unsaturated complex; this can be accomplished via internal rearrangement of the complex. The process of internal rearrangement plays an important role in the chemistry of a variety of complexes and is investigated using ultrafast time resolved infrared spectroscopy, step-scan FTIR spectroscopy and density functional theory modeling. Three different reactions are explored in this work in an effort to expand our basic understanding of organometallic reactions dynamics in solution.
ISBN: 9781109099034Subjects--Topical Terms:
560527
Chemistry, Physical.
The internal rearrangement dynamics of organometallic complexes investigated with ultrafast infrared spectroscopy.
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The rearrangement dynamics of transition metal complexes are of fundamental scientific importance and also of practical industrial relevance being widely used in photo-activated synthesis. The first step after photo-activation is the stabilization of the coordinatively unsaturated complex; this can be accomplished via internal rearrangement of the complex. The process of internal rearrangement plays an important role in the chemistry of a variety of complexes and is investigated using ultrafast time resolved infrared spectroscopy, step-scan FTIR spectroscopy and density functional theory modeling. Three different reactions are explored in this work in an effort to expand our basic understanding of organometallic reactions dynamics in solution.
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