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The kinetics and mechanisms of chlor...

Aleman, Gabriel.

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The kinetics and mechanisms of chlorine atom reactions with alkylbenzenes and alkylnaphthalenes.

Record Type:	Language materials, printed : Monograph/item
Title/Author:	The kinetics and mechanisms of chlorine atom reactions with alkylbenzenes and alkylnaphthalenes./
Author:	Aleman, Gabriel.
Description:	148 p.
Notes:	Chair: Scott Hewitt.
Contained By:	Masters Abstracts International44-01.
Subject:	Chemistry, Analytical. -
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=1428088
ISBN:	9780542220227

The kinetics and mechanisms of chlorine atom reactions with alkylbenzenes and alkylnaphthalenes.
Aleman, Gabriel.

The kinetics and mechanisms of chlorine atom reactions with alkylbenzenes and alkylnaphthalenes. - 148 p.

Chair: Scott Hewitt.

Thesis (M.S.)--California State University, Fullerton, 2006.

The relative rate method was used to study the kinetics and mechanism of Cl atom reactions with a series of alkylbenzenes and alkylnaphthalenes at 298 K and 1 atm. The following rate constants for the alkylbenzenes were obtained (in units of 10-10 cm3molecule -1s-1 with uncertainties of +/-2sigma): ethylbenzene, 1.1 +/- 0.2; n-propylbenzene, 1.9 +/- 0.3; butylbenzene, 2.6 +/- 0.6; o-xylene, 1.5 +/- 0.2; m-xylene, 1.3 +/- 0.1; p-xylene, 1.5 +/- 0.2; 1,3,5-trimethylbenzene, 2.2 +/- 0.4; 1,2,3-trimethylbenzene, 2.5 +/- 0.3; 1,2,4-trimethylbenzene, 2.5 +/- 0.2. The kinetic isotope effect (KIE) measurements and product analyses suggest that the reaction between Cl atoms and alkylbenzenes proceeds via initial hydrogen atom abstraction from the alkyl substituent(s). Preliminary results obtained for the rate constant of the Cl atom reaction with 1-methylnaphthalene (1-MN) in a 21 L reaction cell, (1.3 +/- 0.4) x 10-10 cm3molecule -1s-1, are in excellent agreement with the literature value. The results using a smaller reaction cell varied with initial reactant and reference concentration and were also dependent on the bath gas used. KIE measurements and product analyses of the Cl atom reaction with 1-MN suggest that the mechanism proceeds via abstraction from the methyl group. Implications for fundamental and environmental chemistry will be discussed.

ISBN: 9780542220227Subjects--Topical Terms:

586156
Chemistry, Analytical.

The kinetics and mechanisms of chlorine atom reactions with alkylbenzenes and alkylnaphthalenes.
LDR:02248nam 2200277 a 45 001 974236
005 20110929
008 110929s2006 eng d
020 $a 9780542220227
035 $a (UMI)AAI1428088
035 $a AAI1428088
040 $a UMI $c UMI
100 1 $a Aleman, Gabriel. $3 1298179
245 1 4 $a The kinetics and mechanisms of chlorine atom reactions with alkylbenzenes and alkylnaphthalenes.
300 $a 148 p.
500 $a Chair: Scott Hewitt.
500 $a Source: Masters Abstracts International, Volume: 44-01, page: 0347.
502 $a Thesis (M.S.)--California State University, Fullerton, 2006.
520 $a The relative rate method was used to study the kinetics and mechanism of Cl atom reactions with a series of alkylbenzenes and alkylnaphthalenes at 298 K and 1 atm. The following rate constants for the alkylbenzenes were obtained (in units of 10-10 cm3molecule -1s-1 with uncertainties of +/-2sigma): ethylbenzene, 1.1 +/- 0.2; n-propylbenzene, 1.9 +/- 0.3; butylbenzene, 2.6 +/- 0.6; o-xylene, 1.5 +/- 0.2; m-xylene, 1.3 +/- 0.1; p-xylene, 1.5 +/- 0.2; 1,3,5-trimethylbenzene, 2.2 +/- 0.4; 1,2,3-trimethylbenzene, 2.5 +/- 0.3; 1,2,4-trimethylbenzene, 2.5 +/- 0.2. The kinetic isotope effect (KIE) measurements and product analyses suggest that the reaction between Cl atoms and alkylbenzenes proceeds via initial hydrogen atom abstraction from the alkyl substituent(s). Preliminary results obtained for the rate constant of the Cl atom reaction with 1-methylnaphthalene (1-MN) in a 21 L reaction cell, (1.3 +/- 0.4) x 10-10 cm3molecule -1s-1, are in excellent agreement with the literature value. The results using a smaller reaction cell varied with initial reactant and reference concentration and were also dependent on the bath gas used. KIE measurements and product analyses of the Cl atom reaction with 1-MN suggest that the mechanism proceeds via abstraction from the methyl group. Implications for fundamental and environmental chemistry will be discussed.
590 $a School code: 6060.
650 4 $a Chemistry, Analytical. $3 586156
650 4 $a Chemistry, Physical. $3 560527
690 $a 0486
690 $a 0494
710 2 0 $a California State University, Fullerton. $3 1017845
773 0 $t Masters Abstracts International $g 44-01.
790 $a 6060
790 1 0 $a Hewitt, Scott, $e advisor
791 $a M.S.
792 $a 2006
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=1428088