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Molecular recognition induced small ...

Nakade, Hiroshi.

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Molecular recognition induced small molecule and polymer self-assembly .

Record Type:	Language materials, printed : Monograph/item
Title/Author:	Molecular recognition induced small molecule and polymer self-assembly ./
Author:	Nakade, Hiroshi.
Description:	129 p.
Notes:	Adviser: Vincent M. Rotello.
Contained By:	Dissertation Abstracts International68-03B.
Subject:	Chemistry, Organic. -
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3254919

Molecular recognition induced small molecule and polymer self-assembly .
Nakade, Hiroshi.

Molecular recognition induced small molecule and polymer self-assembly . - 129 p.

Adviser: Vincent M. Rotello.

Thesis (Ph.D.)--University of Massachusetts Amherst, 2007.

Molecular self-assembly offers an effective approach to create highly ordered construct useful in materials science. We have demonstrated that molecular recognition dyads self-assemble into discrete helical structures via chiral translation, and the systems have exhibited liquid crystalline properties mediated by molecular recognition. Through combination of chiral translations, we have been able to highlight cooperative and frustrated self-assembled systems as a consequence of delicate interplay of chiralities. Small chirality changes in self-assembled systems are also essential in liquid crystalline properties to provide well-defined molecular organization. Imparting recognition elements with dendritic blocks enables control over self-assembled structures. In addition, we have demonstrated that complementary alternating copolymers self-assemble into ordered spherical aggregates through cooperative binding and duplex formation.Subjects--Topical Terms:

516206
Chemistry, Organic.

Molecular recognition induced small molecule and polymer self-assembly .
LDR:01807nam 2200265 a 45 001 967453
005 20110915
008 110915s2007 eng d
035 $a (UMI)AAI3254919
035 $a AAI3254919
040 $a UMI $c UMI
100 1 $a Nakade, Hiroshi. $3 1291328
245 1 0 $a Molecular recognition induced small molecule and polymer self-assembly .
300 $a 129 p.
500 $a Adviser: Vincent M. Rotello.
500 $a Source: Dissertation Abstracts International, Volume: 68-03, Section: B, page: 1644.
502 $a Thesis (Ph.D.)--University of Massachusetts Amherst, 2007.
520 $a Molecular self-assembly offers an effective approach to create highly ordered construct useful in materials science. We have demonstrated that molecular recognition dyads self-assemble into discrete helical structures via chiral translation, and the systems have exhibited liquid crystalline properties mediated by molecular recognition. Through combination of chiral translations, we have been able to highlight cooperative and frustrated self-assembled systems as a consequence of delicate interplay of chiralities. Small chirality changes in self-assembled systems are also essential in liquid crystalline properties to provide well-defined molecular organization. Imparting recognition elements with dendritic blocks enables control over self-assembled structures. In addition, we have demonstrated that complementary alternating copolymers self-assemble into ordered spherical aggregates through cooperative binding and duplex formation.
590 $a School code: 0118.
650 4 $a Chemistry, Organic. $3 516206
650 4 $a Chemistry, Polymer. $3 1018428
690 $a 0490
690 $a 0495
710 2 0 $a University of Massachusetts Amherst. $3 1019433
773 0 $t Dissertation Abstracts International $g 68-03B.
790 $a 0118
790 1 0 $a Rotello, Vincent M., $e advisor
791 $a Ph.D.
792 $a 2007
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3254919