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Comprehending structural properties ...

Sivanandan, Kulandaivelu S.

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Comprehending structural properties of dendrimers using new synthetic strategies.

Record Type:	Language materials, printed : Monograph/item
Title/Author:	Comprehending structural properties of dendrimers using new synthetic strategies./
Author:	Sivanandan, Kulandaivelu S.
Description:	203 p.
Notes:	Adviser: S. Thayumanavan.
Contained By:	Dissertation Abstracts International69-02B.
Subject:	Chemistry, Organic. -
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3302230
ISBN:	9780549477112

Comprehending structural properties of dendrimers using new synthetic strategies.
Sivanandan, Kulandaivelu S.

Comprehending structural properties of dendrimers using new synthetic strategies. - 203 p.

Adviser: S. Thayumanavan.

Thesis (Ph.D.)--University of Massachusetts Amherst, 2007.

Three different synthetic approaches for constructing multi-functional dendrimers were described. Using one of the synthetic approaches, dendrimers containing a single photoactive unit at different layers were constructed. The accessibility of these layers for an external molecule was then studied using photo induced electron transfer process (PIET). Similarly, facially amphiphilic dendrimers containing single acetylene functionality at different layers was also synthesized using one of the synthetic approaches. Ferrocene was incorporated in these dendrimers using Huisgen cycloaddition reaction between the dendritic acetylene and azidomethyl ferrocene. Use of electrochemical experiments to measure the accessibility of these layers is suggested. These synthetic strategies will have implications in the area of drug delivery and catalysis.

ISBN: 9780549477112Subjects--Topical Terms:

516206
Chemistry, Organic.

Comprehending structural properties of dendrimers using new synthetic strategies.
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020 $a 9780549477112
035 $a (UMI)AAI3302230
035 $a AAI3302230
040 $a UMI $c UMI
100 1 $a Sivanandan, Kulandaivelu S. $3 1280796
245 1 0 $a Comprehending structural properties of dendrimers using new synthetic strategies.
300 $a 203 p.
500 $a Adviser: S. Thayumanavan.
500 $a Source: Dissertation Abstracts International, Volume: 69-02, Section: B, page: 1019.
502 $a Thesis (Ph.D.)--University of Massachusetts Amherst, 2007.
520 $a Three different synthetic approaches for constructing multi-functional dendrimers were described. Using one of the synthetic approaches, dendrimers containing a single photoactive unit at different layers were constructed. The accessibility of these layers for an external molecule was then studied using photo induced electron transfer process (PIET). Similarly, facially amphiphilic dendrimers containing single acetylene functionality at different layers was also synthesized using one of the synthetic approaches. Ferrocene was incorporated in these dendrimers using Huisgen cycloaddition reaction between the dendritic acetylene and azidomethyl ferrocene. Use of electrochemical experiments to measure the accessibility of these layers is suggested. These synthetic strategies will have implications in the area of drug delivery and catalysis.
590 $a School code: 0118.
650 4 $a Chemistry, Organic. $3 516206
650 4 $a Chemistry, Polymer. $3 1018428
690 $a 0490
690 $a 0495
710 2 $a University of Massachusetts Amherst. $3 1019433
773 0 $t Dissertation Abstracts International $g 69-02B.
790 $a 0118
790 1 0 $a Thayumanavan, S., $e advisor
791 $a Ph.D.
792 $a 2007
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3302230