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The synthesis and evaluation of poly...

Cullen, Chad Michael.

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The synthesis and evaluation of polyaniline/bismuth nanocomposites for use as thermoelectric materials.

Record Type:	Language materials, printed : Monograph/item
Title/Author:	The synthesis and evaluation of polyaniline/bismuth nanocomposites for use as thermoelectric materials./
Author:	Cullen, Chad Michael.
Description:	149 p.
Notes:	Adviser: Alexis Abramson.
Contained By:	Masters Abstracts International46-01.
Subject:	Chemistry, Polymer. -
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=1444956
ISBN:	9780549097556

The synthesis and evaluation of polyaniline/bismuth nanocomposites for use as thermoelectric materials.
Cullen, Chad Michael.

The synthesis and evaluation of polyaniline/bismuth nanocomposites for use as thermoelectric materials. - 149 p.

Adviser: Alexis Abramson.

Thesis (M.S.)--Case Western Reserve University, 2007.

Nanoscale materials have been shown to demonstrate properties radically different from their bulk counterparts. In order to unlock the benefits of these nanoscale effects and produce a new class of conducting polymer thermoelectric materials, bismuth nanoparticles were combined with polyaniline to produce thin film nanocomposites. A method for processing polyaniline and dispersing the nanoparticles throughout the polymer matrix was developed and optimized. The electrical conductivity and Seebeck coefficient of the nanocomposite films were measured, indicating unexpected behavior in each property. This motivated a compositional study of the bismuth nanoparticles via x-ray photoelectron spectroscopy. The results of this study and the effects on the structure of polyaniline were used to explain the unexpected behavior of the thermoelectric properties. In preparation for the study of further polyaniline nanocomposites, a process to synthesize bismuth nanowires was developed. The method was proven successful by studying the nanowires under a scanning electron microscope.

ISBN: 9780549097556Subjects--Topical Terms:

1018428
Chemistry, Polymer.

The synthesis and evaluation of polyaniline/bismuth nanocomposites for use as thermoelectric materials.
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035 $a (UMI)AAI1444956
035 $a AAI1444956
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100 1 $a Cullen, Chad Michael. $3 1278512
245 1 4 $a The synthesis and evaluation of polyaniline/bismuth nanocomposites for use as thermoelectric materials.
300 $a 149 p.
500 $a Adviser: Alexis Abramson.
500 $a Source: Masters Abstracts International, Volume: 46-01, page: 0491.
502 $a Thesis (M.S.)--Case Western Reserve University, 2007.
520 $a Nanoscale materials have been shown to demonstrate properties radically different from their bulk counterparts. In order to unlock the benefits of these nanoscale effects and produce a new class of conducting polymer thermoelectric materials, bismuth nanoparticles were combined with polyaniline to produce thin film nanocomposites. A method for processing polyaniline and dispersing the nanoparticles throughout the polymer matrix was developed and optimized. The electrical conductivity and Seebeck coefficient of the nanocomposite films were measured, indicating unexpected behavior in each property. This motivated a compositional study of the bismuth nanoparticles via x-ray photoelectron spectroscopy. The results of this study and the effects on the structure of polyaniline were used to explain the unexpected behavior of the thermoelectric properties. In preparation for the study of further polyaniline nanocomposites, a process to synthesize bismuth nanowires was developed. The method was proven successful by studying the nanowires under a scanning electron microscope.
590 $a School code: 0042.
650 4 $a Chemistry, Polymer. $3 1018428
650 4 $a Engineering, Materials Science. $3 1017759
650 4 $a Engineering, Mechanical. $3 783786
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710 2 $a Case Western Reserve University. $3 1017714
773 0 $t Masters Abstracts International $g 46-01.
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856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=1444956