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Synthesis and characterization of no...
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Brown, Jason Rogers.
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Synthesis and characterization of novel lithium ion battery cathode materials produced via assisted soft chemistry.
Record Type:
Language materials, printed : Monograph/item
Title/Author:
Synthesis and characterization of novel lithium ion battery cathode materials produced via assisted soft chemistry./
Author:
Brown, Jason Rogers.
Description:
101 p.
Notes:
Chair: M. David Curtis.
Contained By:
Dissertation Abstracts International63-10B.
Subject:
Chemistry, Inorganic. -
Online resource:
http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3068833
ISBN:
0493885048
Synthesis and characterization of novel lithium ion battery cathode materials produced via assisted soft chemistry.
Brown, Jason Rogers.
Synthesis and characterization of novel lithium ion battery cathode materials produced via assisted soft chemistry.
- 101 p.
Chair: M. David Curtis.
Thesis (Ph.D.)--University of Michigan, 2002.
Lithium transition metal oxides, LiMO<sub>2</sub>, are the most promising positive electrode material for lithium ion batteries because of their high charge capacity (>150 mAh/g) and facile lithium ion diffusion in their lattice. A new synthetic method for preparation of stabilized LiMO<sub>2</sub> has been developed as “<italic>Assisted Soft Chemistry</italic>.” Using this technique, the lithium in LiMO<sub>2</sub> can be exchanged partially for zinc or gallium. Powder X-ray diffraction studies verify that zinc or gallium doped Li<sub>1−y</sub>Zn<sub>y/2</sub>MO<sub>2</sub> and Li<sub> 1−y</sub>Ga<sub>y/3</sub>MO<sub>2</sub>, where ‘y’ equals 0.15 or 0.30 and ‘M’ is Co<sub>0.7</sub>Ni<sub>0.3</sub>, Co<sub> 0.3</sub>Ni<sub>0.7</sub>, or Ni have the same lamellar structure as their respective non-doped precursors, LiCo<sub>0.7</sub>Ni<sub>0.3</sub>O<sub> 2</sub>, LiCo<sub>0.3</sub>Ni<sub>0.7</sub>O<sub>2</sub>, and LiNiO<sub>2 </sub>. Observed electrical conductivities were determined by AC impedance spectroscopy and two point probe measurements and indicate marked electronic conductivity enhancement for the Zn substituted sample in the range of 1 to 2 orders of magnitude. Electrochemical charge/discharge profiles of the new cathode materials have shown reversible lithium insertion and extraction processes with charge capacity exceeding 150 mAh/g. The DSC analyses of the zinc-doped cathode materials show improved thermal stability of the new cathode materials when compared to non-doped commercial cathode materials.
ISBN: 0493885048Subjects--Topical Terms:
517253
Chemistry, Inorganic.
Synthesis and characterization of novel lithium ion battery cathode materials produced via assisted soft chemistry.
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Synthesis and characterization of novel lithium ion battery cathode materials produced via assisted soft chemistry.
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101 p.
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Chair: M. David Curtis.
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Source: Dissertation Abstracts International, Volume: 63-10, Section: B, page: 4669.
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Thesis (Ph.D.)--University of Michigan, 2002.
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Lithium transition metal oxides, LiMO<sub>2</sub>, are the most promising positive electrode material for lithium ion batteries because of their high charge capacity (>150 mAh/g) and facile lithium ion diffusion in their lattice. A new synthetic method for preparation of stabilized LiMO<sub>2</sub> has been developed as “<italic>Assisted Soft Chemistry</italic>.” Using this technique, the lithium in LiMO<sub>2</sub> can be exchanged partially for zinc or gallium. Powder X-ray diffraction studies verify that zinc or gallium doped Li<sub>1−y</sub>Zn<sub>y/2</sub>MO<sub>2</sub> and Li<sub> 1−y</sub>Ga<sub>y/3</sub>MO<sub>2</sub>, where ‘y’ equals 0.15 or 0.30 and ‘M’ is Co<sub>0.7</sub>Ni<sub>0.3</sub>, Co<sub> 0.3</sub>Ni<sub>0.7</sub>, or Ni have the same lamellar structure as their respective non-doped precursors, LiCo<sub>0.7</sub>Ni<sub>0.3</sub>O<sub> 2</sub>, LiCo<sub>0.3</sub>Ni<sub>0.7</sub>O<sub>2</sub>, and LiNiO<sub>2 </sub>. Observed electrical conductivities were determined by AC impedance spectroscopy and two point probe measurements and indicate marked electronic conductivity enhancement for the Zn substituted sample in the range of 1 to 2 orders of magnitude. Electrochemical charge/discharge profiles of the new cathode materials have shown reversible lithium insertion and extraction processes with charge capacity exceeding 150 mAh/g. The DSC analyses of the zinc-doped cathode materials show improved thermal stability of the new cathode materials when compared to non-doped commercial cathode materials.
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http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3068833
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