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Design and characterization of a mul...

University of Michigan.

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Design and characterization of a multi-vapor preconcentrator for a micro-scale gas chromatograph.

紀錄類型:	書目-電子資源 : Monograph/item
正題名/作者:	Design and characterization of a multi-vapor preconcentrator for a micro-scale gas chromatograph./
作者:	Veeneman, Rebecca A.
面頁冊數:	186 p.
附註:	Adviser: Edward T. Zellers.
Contained By:	Dissertation Abstracts International70-04B.
標題:	Chemistry, Analytical. -
電子資源:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3354202
ISBN:	9781109119312

Design and characterization of a multi-vapor preconcentrator for a micro-scale gas chromatograph.
Veeneman, Rebecca A.

Design and characterization of a multi-vapor preconcentrator for a micro-scale gas chromatograph. - 186 p.

Adviser: Edward T. Zellers.

Thesis (Ph.D.)--University of Michigan, 2009.

This dissertation addresses several elements critical to the design and implementation of adsorbent-packed micro-scale preconcentrator/focuser (microPCF) intended for integration into a microfabricated gas chromatograph (microGC). Assessment of the adsorption of volatile organic compounds (VOCs) on two commercial graphitized carbons at air concentrations in the parts-per-billion (ppb) range in the context of the Dubinin-Radushkevich (DR) isotherm model revealed an unusual bi-modal distribution of characteristic adsorption energies for most vapors. Systematic trends in observed VOC behaviors on these non-microporous adsorbents are rationalized in terms of the volatility and polarity of the adsorbates, and the relative strength of adsorbate-absorbent interactions over different ranges of surface coverage. The attempt to apply the DR model at such low VOC concentrations is unprecedented, and the results highlight several constraints on its applicability for estimating the mass of adsorbent required for efficient microPCF performance.

ISBN: 9781109119312Subjects--Topical Terms:

586156
Chemistry, Analytical.

Design and characterization of a multi-vapor preconcentrator for a micro-scale gas chromatograph.
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245 1 0 $a Design and characterization of a multi-vapor preconcentrator for a micro-scale gas chromatograph.
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520 $a This dissertation addresses several elements critical to the design and implementation of adsorbent-packed micro-scale preconcentrator/focuser (microPCF) intended for integration into a microfabricated gas chromatograph (microGC). Assessment of the adsorption of volatile organic compounds (VOCs) on two commercial graphitized carbons at air concentrations in the parts-per-billion (ppb) range in the context of the Dubinin-Radushkevich (DR) isotherm model revealed an unusual bi-modal distribution of characteristic adsorption energies for most vapors. Systematic trends in observed VOC behaviors on these non-microporous adsorbents are rationalized in terms of the volatility and polarity of the adsorbates, and the relative strength of adsorbate-absorbent interactions over different ranges of surface coverage. The attempt to apply the DR model at such low VOC concentrations is unprecedented, and the results highlight several constraints on its applicability for estimating the mass of adsorbent required for efficient microPCF performance.
520 $a The effect of flow velocity on the capacity of an adsorbent-packed microPCF containing &sim;3 mg of adsorbent was characterized along with a similarly packed device of a more conventional design. It was shown for two representative vapors that below a bed residence time of 8 msec, corresponding to volumetric flow rates of 30 mL/min, fractional breakthrough occurred almost immediately. The critical bed residence time differed between the vapors in a predictable manner, and guidelines were established on the basis of these results for limiting the operational flow rates of microPCFs. Using the conventional PCF a series of tests was then performed to explore the capacity of the device upon exposure to binary mixtures comprising vapors with different volatility and structure. Comparison of the results with those expected on the basis of recently developed models derived from larger adsorbent beds revealed significant discrepancies, which suggests that improvements to such models are needed; however several factors were revealed that may facilitate future efforts to improve the models. These first attempts to verify the application of established thermodynamic and kinetic models of adsorption to microPCFs containing low-mg quantities of adsorbents have produced important results critical to their design and implementation in microanalytical systems for VOC mixtures.
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