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Polymer colloids for catalysis in fl...
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Oklahoma State University., Chemistry.
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Polymer colloids for catalysis in fluorous media and for colloidal crystalline arrays.
Record Type:
Language materials, printed : Monograph/item
Title/Author:
Polymer colloids for catalysis in fluorous media and for colloidal crystalline arrays./
Author:
Karnati, Rangarani.
Description:
100 p.
Notes:
Adviser: Warren T. Ford.
Contained By:
Dissertation Abstracts International69-12B.
Subject:
Chemistry, Polymer. -
Online resource:
http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3341740
ISBN:
9780549975090
Polymer colloids for catalysis in fluorous media and for colloidal crystalline arrays.
Karnati, Rangarani.
Polymer colloids for catalysis in fluorous media and for colloidal crystalline arrays.
- 100 p.
Adviser: Warren T. Ford.
Thesis (Ph.D.)--Oklahoma State University, 2009.
Scope and Method of Study. Monodisperse charged polymer colloids in aqueous and non-aqueous dispersions have potential applications as membranes and catalysts. We chose poly(ethylhexyl methacrylate) particles containing quaternary ammonium ions and poly(methyl methacrylate) polymer particles for the catalytic and colloidal crystalline filter fabrication applications. Micron sized poly(ethylhexyl methacrylate) (EHMA) cross-linked copolymers in fluorinated solvents were synthesized by dispersion polymerization using microwave heating for the catalytic applications. Sub-micron sized poly(methyl methacrylate) (PMMA) core-shell latexes in aqueous media were made by emulsifier-free emulsion polymerization for colloidal crystal films (CCF) making.
ISBN: 9780549975090Subjects--Topical Terms:
1018428
Chemistry, Polymer.
Polymer colloids for catalysis in fluorous media and for colloidal crystalline arrays.
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Karnati, Rangarani.
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Polymer colloids for catalysis in fluorous media and for colloidal crystalline arrays.
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100 p.
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Adviser: Warren T. Ford.
500
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Source: Dissertation Abstracts International, Volume: 69-12, Section: B, page: 7538.
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Thesis (Ph.D.)--Oklahoma State University, 2009.
520
$a
Scope and Method of Study. Monodisperse charged polymer colloids in aqueous and non-aqueous dispersions have potential applications as membranes and catalysts. We chose poly(ethylhexyl methacrylate) particles containing quaternary ammonium ions and poly(methyl methacrylate) polymer particles for the catalytic and colloidal crystalline filter fabrication applications. Micron sized poly(ethylhexyl methacrylate) (EHMA) cross-linked copolymers in fluorinated solvents were synthesized by dispersion polymerization using microwave heating for the catalytic applications. Sub-micron sized poly(methyl methacrylate) (PMMA) core-shell latexes in aqueous media were made by emulsifier-free emulsion polymerization for colloidal crystal films (CCF) making.
520
$a
Findings and Conclusions. Cationic EHMA copolymers slightly increased the hydrolysis of p-nitrophenyl hexanoate in fluorous media compared to the control experiment which lacked the polymer particles. PMMA CCF's fabricated by gravitational sedimentation method contained monodisperse FCC packed domains of 5-10 microm, point defects, and grain boundaries.
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School code: 0664.
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Chemistry, Polymer.
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Berlin, Kenneth Darrell
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committee member
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committee member
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Ford, Warren T.,
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advisor
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Matts, Robert L.
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committee member
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Slaughter, LeGrande M.
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Ph.D.
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2009
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http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3341740
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