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Thermodynamics of Critical Rare Eart...

Reece, Margaret Elizabeth,

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Thermodynamics of Critical Rare Earth Minerals /

Record Type:	Electronic resources : Monograph/item
Title/Author:	Thermodynamics of Critical Rare Earth Minerals // Margaret Elizabeth Reece.
Author:	Reece, Margaret Elizabeth,
Description:	1 electronic resource (123 pages)
Notes:	Source: Dissertations Abstracts International, Volume: 85-09, Section: B.
Contained By:	Dissertations Abstracts International85-09B.
Subject:	Chemistry. -
Online resource:	https://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=30691645
ISBN:	9798381849783

Thermodynamics of Critical Rare Earth Minerals /
Reece, Margaret Elizabeth,

Thermodynamics of Critical Rare Earth Minerals /Margaret Elizabeth Reece. - 1 electronic resource (123 pages)

Source: Dissertations Abstracts International, Volume: 85-09, Section: B.

Rare earth elements are a critical resource for advancing technologies, including nuclear waste applications. Economically minable sources of this element group is limited, and the determination of geologic behavior applied to find viable deposits is a large task that requires an in-depth understanding of thermodynamic behavior of involved species. A variety of mineral structures that host these elements were studied for derivation of thermodynamic properties that relate to the geologic stability, but also natural behaviors and potential applications as nuclear wastes. Solid phase thermodynamic characterization was employed to determine surface characteristics of pyrochlore minerals, aqueous phase solubility studies were performed in carbonate-bearing solutions for the common source minerals of monazite and bastnäsite, and solid-solution series were studied structurally and calorimetrically to preliminarily characterize natural solid-solution phosphate minerals. The solid phase characterizations included comparisons of energetics to cationic radii. Aqueous carbonate complexes were identified in Nd-carbonate systems bearing phosphate and fluoride. This information will aid in the genetic modeling of rare earth minerals and the behavior of mineral waste hosts in extreme conditions.

English

ISBN: 9798381849783Subjects--Topical Terms:

516420
Chemistry.
Subjects--Index Terms:

Enthalpy

Thermodynamics of Critical Rare Earth Minerals /
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020 $a 9798381849783
035 $a (MiAaPQD)AAI30691645
035 $a AAI30691645
040 $a MiAaPQD $b eng $c MiAaPQD $e rda
100 1 $a Reece, Margaret Elizabeth, $e author. $0 (orcid)0009-0001-0014-4341 $3 3814492
245 1 0 $a Thermodynamics of Critical Rare Earth Minerals / $c Margaret Elizabeth Reece.
264 1 $a Ann Arbor : $b ProQuest Dissertations & Theses, $c 2023
300 $a 1 electronic resource (123 pages)
336 $a text $b txt $2 rdacontent
337 $a computer $b c $2 rdamedia
338 $a online resource $b cr $2 rdacarrier
500 $a Source: Dissertations Abstracts International, Volume: 85-09, Section: B.
500 $a Advisors: Guo, Xiaofeng Committee members: Migdissov, Artaches; Boncella, James; Zhang, Qiang.
502 $b Ph.D. $c Washington State University $d 2023.
520 $a Rare earth elements are a critical resource for advancing technologies, including nuclear waste applications. Economically minable sources of this element group is limited, and the determination of geologic behavior applied to find viable deposits is a large task that requires an in-depth understanding of thermodynamic behavior of involved species. A variety of mineral structures that host these elements were studied for derivation of thermodynamic properties that relate to the geologic stability, but also natural behaviors and potential applications as nuclear wastes. Solid phase thermodynamic characterization was employed to determine surface characteristics of pyrochlore minerals, aqueous phase solubility studies were performed in carbonate-bearing solutions for the common source minerals of monazite and bastnäsite, and solid-solution series were studied structurally and calorimetrically to preliminarily characterize natural solid-solution phosphate minerals. The solid phase characterizations included comparisons of energetics to cationic radii. Aqueous carbonate complexes were identified in Nd-carbonate systems bearing phosphate and fluoride. This information will aid in the genetic modeling of rare earth minerals and the behavior of mineral waste hosts in extreme conditions.
546 $a English
590 $a School code: 0251
650 4 $a Chemistry. $3 516420
650 4 $a Nuclear chemistry. $3 643077
650 4 $a Geochemistry. $3 539092
650 4 $a Mineralogy. $3 516743
653 $a Enthalpy
653 $a Minerals
653 $a Rare earth elements
653 $a Solubility
653 $a Thermodynamics
690 $a 0485
690 $a 0738
690 $a 0996
690 $a 0411
710 2 $a Washington State University. $b Department of Chemistry. $e degree granting institution. $3 3814493
720 1 $a Guo, Xiaofeng $e degree supervisor.
773 0 $t Dissertations Abstracts International $g 85-09B.
790 $a 0251
791 $a Ph.D.
792 $a 2023
856 4 0 $u https://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=30691645