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Structure-Property Relationships in ...
~
Cooper, Christopher Brittain.
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Structure-Property Relationships in Dynamic Polymer Networks.
Record Type:
Electronic resources : Monograph/item
Title/Author:
Structure-Property Relationships in Dynamic Polymer Networks./
Author:
Cooper, Christopher Brittain.
Published:
Ann Arbor : ProQuest Dissertations & Theses, : 2023,
Description:
154 p.
Notes:
Source: Dissertations Abstracts International, Volume: 85-11, Section: B.
Contained By:
Dissertations Abstracts International85-11B.
Subject:
Hydrogen bonds. -
Online resource:
https://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=31049677
ISBN:
9798382636375
Structure-Property Relationships in Dynamic Polymer Networks.
Cooper, Christopher Brittain.
Structure-Property Relationships in Dynamic Polymer Networks.
- Ann Arbor : ProQuest Dissertations & Theses, 2023 - 154 p.
Source: Dissertations Abstracts International, Volume: 85-11, Section: B.
Thesis (Ph.D.)--Stanford University, 2023.
Many emerging applications including wearable electronics and e-skins, soft robotics and actuators, and biomaterials, require material platforms with precisely controlled mechanical, electrical, thermal, and optical properties. The practical realization of devices for these applications is often restricted not by the lack of novel designs, but rather by the sparsity of materials with the required properties. Dynamic polymers, which employ both permanent and reversible linkages, offer a promising platform for the design of new materials due to their highly tunable and responsive chemical structures.This dissertation explores structure-property relationships in different dynamic polymer networks with well-defined polymer design and is structured as follows. Chapter 1 introduces the concept of dynamic polymers, provides comparisons to supramolecular polymers and segmented block copolymers, and concludes with emerging applications for these systems. Chapter 2 examines the molecular design rules for spontaneous self-assembly of periodic dynamic polymers into supramolecular nanofibers. Chapter 3 discusses the phenomenon of strain-induced supramolecular structures exhibited by entangled periodic dynamic polymers. Chapter 4 highlights how the clustered nanomorphology exhibited by periodic dynamic polymers can be used to design recyclable underwater adhesives. Chapter 5 explains how immiscible dynamic polymers can be used to achieve autonomous alignment of multilayered soft electronics. Chapter 6 concludes with key observations and on the future outlook of next-generation materials.
ISBN: 9798382636375Subjects--Topical Terms:
768332
Hydrogen bonds.
Structure-Property Relationships in Dynamic Polymer Networks.
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Many emerging applications including wearable electronics and e-skins, soft robotics and actuators, and biomaterials, require material platforms with precisely controlled mechanical, electrical, thermal, and optical properties. The practical realization of devices for these applications is often restricted not by the lack of novel designs, but rather by the sparsity of materials with the required properties. Dynamic polymers, which employ both permanent and reversible linkages, offer a promising platform for the design of new materials due to their highly tunable and responsive chemical structures.This dissertation explores structure-property relationships in different dynamic polymer networks with well-defined polymer design and is structured as follows. Chapter 1 introduces the concept of dynamic polymers, provides comparisons to supramolecular polymers and segmented block copolymers, and concludes with emerging applications for these systems. Chapter 2 examines the molecular design rules for spontaneous self-assembly of periodic dynamic polymers into supramolecular nanofibers. Chapter 3 discusses the phenomenon of strain-induced supramolecular structures exhibited by entangled periodic dynamic polymers. Chapter 4 highlights how the clustered nanomorphology exhibited by periodic dynamic polymers can be used to design recyclable underwater adhesives. Chapter 5 explains how immiscible dynamic polymers can be used to achieve autonomous alignment of multilayered soft electronics. Chapter 6 concludes with key observations and on the future outlook of next-generation materials.
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https://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=31049677
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