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Identifying Energy-Structure-Propert...

Hanna, Sylvia Lorraine.

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Identifying Energy-Structure-Property Relationships in Uranium Metal-Organic Frameworks through Their Dynamic Crystalline Structural Transformations.

紀錄類型:	書目-電子資源 : Monograph/item
正題名/作者:	Identifying Energy-Structure-Property Relationships in Uranium Metal-Organic Frameworks through Their Dynamic Crystalline Structural Transformations./
作者:	Hanna, Sylvia Lorraine.
出版者:	Ann Arbor : ProQuest Dissertations & Theses, : 2023,
面頁冊數:	442 p.
附註:	Source: Dissertations Abstracts International, Volume: 84-09, Section: B.
Contained By:	Dissertations Abstracts International84-09B.
標題:	Chemistry. -
電子資源:	https://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=30249970
ISBN:	9798377642787

Identifying Energy-Structure-Property Relationships in Uranium Metal-Organic Frameworks through Their Dynamic Crystalline Structural Transformations.
Hanna, Sylvia Lorraine.

Identifying Energy-Structure-Property Relationships in Uranium Metal-Organic Frameworks through Their Dynamic Crystalline Structural Transformations. - Ann Arbor : ProQuest Dissertations & Theses, 2023 - 442 p.

Source: Dissertations Abstracts International, Volume: 84-09, Section: B.

Thesis (Ph.D.)--Northwestern University, 2023.

This item must not be sold to any third party vendors.

Uranium is a unique, multifaceted element that possesses rich chemistry and promise for challenging reactions. Pressing demands within nuclear stockpile stewardship and the nuclear energy sector call for development of this relatively understudied element. Uranium metal-organic frameworks (U-MOFs), a class of nanoscale hybrid materials, harness the exceptional attributes of uranium while also further developing its fundamental chemistry. While structure-property relationships in U-MOFs correlate the physical arrangement of atoms in a U-MOF lattice to the resulting material behavior, energy-structure-property relationships allow researchers to rationalize these correlations. In this thesis, I identify and investigate energy-structure-property relationships in U-MOFs through the study of their dynamic crystalline structural transformations. Chapters 2-4 illustrate separate aspects of energy-structure-property relationships as individual vignettes (Chapter 2: structure-property relationships, Chapter 3: energy-structure relationships, Chapter 4: energy-property relationships). Finally, Chapter 5 ties energy, structure, and property together to explain why structure produces function. This thesis ultimately offers a deeper understanding of U-MOF behavior, discovers novel U-MOF phenomena, and delineates design rules for the budding U-MOF field.

ISBN: 9798377642787Subjects--Topical Terms:

516420
Chemistry.
Subjects--Index Terms:

Metal-organic frameworks

Identifying Energy-Structure-Property Relationships in Uranium Metal-Organic Frameworks through Their Dynamic Crystalline Structural Transformations.
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