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Spontaneous Patterning Via Frontal Polymerization.

Record Type:	Electronic resources : Monograph/item
Title/Author:	Spontaneous Patterning Via Frontal Polymerization./
Author:	Dearborn, Mason Allen.
Description:	1 online resource (96 pages)
Notes:	Source: Dissertations Abstracts International, Volume: 84-09, Section: B.
Contained By:	Dissertations Abstracts International84-09B.
Subject:	Polymer chemistry. -
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=30245948click for full text (PQDT)
ISBN:	9798377640448

Spontaneous Patterning Via Frontal Polymerization.
Dearborn, Mason Allen.

Spontaneous Patterning Via Frontal Polymerization. - 1 online resource (96 pages)

Source: Dissertations Abstracts International, Volume: 84-09, Section: B.

Thesis (Ph.D.)--The University of Chicago, 2023.

Includes bibliographical references

Traditional composite manufacturing is a multi-step process limited to fabrication of uniform parts with a high time and energy cost. Patterning of materials with spatial control of mechanical properties would enable fabrication of more complex parts with unique functionality for applications beyond what is currently possible. Reaction-diffusion processes have demonstrated potential for creating patterned materials and are herein explored within an advanced method of fabricating high-performance polymeric materials and composites - frontal polymerization. Frontal polymerization (FP) uses a self-propagating exothermic reaction wave to create thermosetting polymeric and composite parts with zero energy input after simple thermal initiation without sacrificing mechanical properties, offering an alternative to traditional autoclave curing. Currently, FP is only used to create parts with uniform properties throughout, limiting the applicability of fabricated parts. The work reported herein develops tools for modulating reaction-diffusion patterning for spatial control of mechanical properties across parts fabricated via the frontal ring-opening metathesis polymerization (FROMP) of dicyclopentadiene (DCPD) and 1,5-cyclooctadiene (COD), enabling more advanced designs in one processing step.Videos and infrared videos (Movies S1-11) showing the propagation of fronts in Chapters 2 and 4 were provided outside this document as supplementary files.

Electronic reproduction.
Ann Arbor, Mich. :
ProQuest,
2023

Mode of access: World Wide Web

ISBN: 9798377640448Subjects--Topical Terms:

3173488
Polymer chemistry.
Subjects--Index Terms:

CompositesIndex Terms--Genre/Form:

542853
Electronic books.

Spontaneous Patterning Via Frontal Polymerization.
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245 1 0 $a Spontaneous Patterning Via Frontal Polymerization.
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500 $a Source: Dissertations Abstracts International, Volume: 84-09, Section: B.
500 $a Includes supplementary digital materials.
500 $a Advisor: Esser-Kahn, Aaron P.
502 $a Thesis (Ph.D.)--The University of Chicago, 2023.
504 $a Includes bibliographical references
520 $a Traditional composite manufacturing is a multi-step process limited to fabrication of uniform parts with a high time and energy cost. Patterning of materials with spatial control of mechanical properties would enable fabrication of more complex parts with unique functionality for applications beyond what is currently possible. Reaction-diffusion processes have demonstrated potential for creating patterned materials and are herein explored within an advanced method of fabricating high-performance polymeric materials and composites - frontal polymerization. Frontal polymerization (FP) uses a self-propagating exothermic reaction wave to create thermosetting polymeric and composite parts with zero energy input after simple thermal initiation without sacrificing mechanical properties, offering an alternative to traditional autoclave curing. Currently, FP is only used to create parts with uniform properties throughout, limiting the applicability of fabricated parts. The work reported herein develops tools for modulating reaction-diffusion patterning for spatial control of mechanical properties across parts fabricated via the frontal ring-opening metathesis polymerization (FROMP) of dicyclopentadiene (DCPD) and 1,5-cyclooctadiene (COD), enabling more advanced designs in one processing step.Videos and infrared videos (Movies S1-11) showing the propagation of fronts in Chapters 2 and 4 were provided outside this document as supplementary files.
533 $a Electronic reproduction. $b Ann Arbor, Mich. : $c ProQuest, $d 2023
538 $a Mode of access: World Wide Web
650 4 $a Polymer chemistry. $3 3173488
650 4 $a Chemical engineering. $3 560457
650 4 $a Materials science. $3 543314
653 $a Composites
653 $a Frontal polymerization
653 $a Composite manufacturing
653 $a Morphogenesis
653 $a Patterning
653 $a Polymers
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690 $a 0794
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710 2 $a The University of Chicago. $b Molecular Engineering. $3 3192669
773 0 $t Dissertations Abstracts International $g 84-09B.
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=30245948 $z click for full text (PQDT)