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Hypervalent Iodine-Based Supramolecular Materials.
Record Type:
Electronic resources : Monograph/item
Title/Author:
Hypervalent Iodine-Based Supramolecular Materials./
Author:
Hill, Christopher.
Description:
1 online resource (71 pages)
Notes:
Source: Masters Abstracts International, Volume: 84-02.
Contained By:
Masters Abstracts International84-02.
Subject:
Organic chemistry. -
Online resource:
http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=29064195click for full text (PQDT)
ISBN:
9798837527098
Hypervalent Iodine-Based Supramolecular Materials.
Hill, Christopher.
Hypervalent Iodine-Based Supramolecular Materials.
- 1 online resource (71 pages)
Source: Masters Abstracts International, Volume: 84-02.
Thesis (M.S.)--Southern Illinois University at Carbondale, 2022.
Includes bibliographical references
This research is aimed at preparing new materials based on supramolecular self-assembly of hypervalent iodine species. Self-assembly via secondary bonding of hypervalent iodine, is a concept that has little been explored in materials design. In this research, polymers bearing iodine functional groups and polymers based on functional initiators containing iodine were synthesized to prepare supramolecular complexes. The reversibility of the secondary bonds is considered, based on oxidation/reduction of the hypervalent iodine core. Controlled radical polymerizations (ATRP) were utilized to prepare polymers with hypervalent iodine functionality. Access to motifs including star-shaped polymers, and cross-linked polymers via intermolecular secondary bonding, are discussed in this work.
Electronic reproduction.
Ann Arbor, Mich. :
ProQuest,
2023
Mode of access: World Wide Web
ISBN: 9798837527098Subjects--Topical Terms:
523952
Organic chemistry.
Subjects--Index Terms:
HypervalentIndex Terms--Genre/Form:
542853
Electronic books.
Hypervalent Iodine-Based Supramolecular Materials.
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Advisor: Plunkett, Kyle N.
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Includes bibliographical references
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This research is aimed at preparing new materials based on supramolecular self-assembly of hypervalent iodine species. Self-assembly via secondary bonding of hypervalent iodine, is a concept that has little been explored in materials design. In this research, polymers bearing iodine functional groups and polymers based on functional initiators containing iodine were synthesized to prepare supramolecular complexes. The reversibility of the secondary bonds is considered, based on oxidation/reduction of the hypervalent iodine core. Controlled radical polymerizations (ATRP) were utilized to prepare polymers with hypervalent iodine functionality. Access to motifs including star-shaped polymers, and cross-linked polymers via intermolecular secondary bonding, are discussed in this work.
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http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=29064195
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click for full text (PQDT)
based on 0 review(s)
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