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Molecular Orientation and Structure of Hydrogen Bonds at Water Interfaces.

Record Type:	Electronic resources : Monograph/item
Title/Author:	Molecular Orientation and Structure of Hydrogen Bonds at Water Interfaces./
Author:	Dutta, Chayan.
Published:	Ann Arbor : ProQuest Dissertations & Theses, : 2017,
Description:	190 p.
Notes:	Source: Dissertations Abstracts International, Volume: 81-12.
Contained By:	Dissertations Abstracts International81-12.
Subject:	Physical chemistry. -
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=27806526
ISBN:	9781392662229

Molecular Orientation and Structure of Hydrogen Bonds at Water Interfaces.
Dutta, Chayan.

Molecular Orientation and Structure of Hydrogen Bonds at Water Interfaces. - Ann Arbor : ProQuest Dissertations & Theses, 2017 - 190 p.

Source: Dissertations Abstracts International, Volume: 81-12.

Thesis (Ph.D.)--University of Southern California, 2017.

This item must not be sold to any third party vendors.

The unique ability of water to form extended hydrogen bond network in the bulk environment is responsible for many unusual physical properties of liquid water. This extended hydrogen bond network is terminated at the interface producing an inherent inhomogeneity in structure, orientation and distribution of hydrogen bonds at the interface. Because of these intrinsic properties interfacial water plays a signiﬁcant role in a variety of systems, e.g., biological membranes, environmental interfaces, electrochemical interfaces, heterogeneous catalysis etc. Understanding the basic interactions of water at the interface is crucial. We have used surface sensitive spectroscopic techniques to investigate into the nature of hydrogen bonds and molecular orientations at the interface. This thesis is mainly focused on assigning the water bending mode at the air/water interface, establishing the bend mode as a complementary probe of hydrogen bonding and investigating molecular orientation of different hydrogen bonded species at neutral interfaces, chemically and electrochemically charged surfaces and in micro-emulsion conﬁnement.

ISBN: 9781392662229Subjects--Topical Terms:

1981412
Physical chemistry.
Subjects--Index Terms:

Hydrogen bonding

Molecular Orientation and Structure of Hydrogen Bonds at Water Interfaces.
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245 1 0 $a Molecular Orientation and Structure of Hydrogen Bonds at Water Interfaces.
260 1 $a Ann Arbor : $b ProQuest Dissertations & Theses, $c 2017
300 $a 190 p.
500 $a Source: Dissertations Abstracts International, Volume: 81-12.
500 $a Advisor: Benderskii, Alexander.
502 $a Thesis (Ph.D.)--University of Southern California, 2017.
506 $a This item must not be sold to any third party vendors.
520 $a The unique ability of water to form extended hydrogen bond network in the bulk environment is responsible for many unusual physical properties of liquid water. This extended hydrogen bond network is terminated at the interface producing an inherent inhomogeneity in structure, orientation and distribution of hydrogen bonds at the interface. Because of these intrinsic properties interfacial water plays a signiﬁcant role in a variety of systems, e.g., biological membranes, environmental interfaces, electrochemical interfaces, heterogeneous catalysis etc. Understanding the basic interactions of water at the interface is crucial. We have used surface sensitive spectroscopic techniques to investigate into the nature of hydrogen bonds and molecular orientations at the interface. This thesis is mainly focused on assigning the water bending mode at the air/water interface, establishing the bend mode as a complementary probe of hydrogen bonding and investigating molecular orientation of different hydrogen bonded species at neutral interfaces, chemically and electrochemically charged surfaces and in micro-emulsion conﬁnement.
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650 4 $a Physical chemistry. $3 1981412
650 4 $a Molecular chemistry. $3 1071612
653 $a Hydrogen bonding
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