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Removal of Heavy Metals Using Novel ...

Joseph, Lesley.

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Removal of Heavy Metals Using Novel Adsorbent Materials.

Record Type:	Electronic resources : Monograph/item
Title/Author:	Removal of Heavy Metals Using Novel Adsorbent Materials./
Author:	Joseph, Lesley.
Published:	Ann Arbor : ProQuest Dissertations & Theses, : 2021,
Description:	219 p.
Notes:	Source: Dissertations Abstracts International, Volume: 83-03, Section: B.
Contained By:	Dissertations Abstracts International83-03B.
Subject:	Environmental engineering. -
Online resource:	https://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=28411440
ISBN:	9798538155019

Removal of Heavy Metals Using Novel Adsorbent Materials.
Joseph, Lesley.

Removal of Heavy Metals Using Novel Adsorbent Materials. - Ann Arbor : ProQuest Dissertations & Theses, 2021 - 219 p.

Source: Dissertations Abstracts International, Volume: 83-03, Section: B.

Thesis (Ph.D.)--University of South Carolina, 2021.

This item must not be sold to any third party vendors.

Heavy metal contamination is a growing concern throughout the world, particularly as industrial and urban activities have increased. Inadequate water and wastewater treatment, coupled with increased industrial activity, have led to increased heavy metal contamination in rivers, lakes, and other water sources in developing countries. To address these concerns, a significant amount of research has been conducted on various novel adsorbents to evaluate their ability to remove heavy metals. Thus, in this study, MIL-100(Fe) and MIL-101(Cr) are fabricated and investigated to determine their ability to remove copper (Cu2+), cadmium (Cd2+), and lead (Pb2+) from aqueous solution. The experimental data fit most closely to the Freundlich model, followed closely by the Linear isotherm model. However, the values for the Freundlich parameter n were close to 1, which suggests that the adsorption followed the Linear isotherm model. The KLIN coefficient [(mg/g)/(mg/L)] for the Linear isotherm model was the largest for Cu2+, followed by Cd2+ and Pb2+. MIL-100(Fe) and MIL-101(Cr) exhibited fast adsorption kinetics, achieving equilibrium in approximately 0.5 hours. Electrostatic interactions were determined to be the dominant adsorption mechanism for the removal of Cu2+, Cd2+, and Pb2+ by MIL-100(Fe) and MIL-101(Cr), which is consistent with similar adsorption studies. This study shows that MIL-100(Fe) and MIL-101(Cr) are effective adsorbents for the removal of heavy metals from aqueous solution.

ISBN: 9798538155019Subjects--Topical Terms:

548583
Environmental engineering.
Subjects--Index Terms:

Adsorption

Removal of Heavy Metals Using Novel Adsorbent Materials.
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245 1 0 $a Removal of Heavy Metals Using Novel Adsorbent Materials.
260 1 $a Ann Arbor : $b ProQuest Dissertations & Theses, $c 2021
300 $a 219 p.
500 $a Source: Dissertations Abstracts International, Volume: 83-03, Section: B.
500 $a Advisor: Yoon, Yeomin.
502 $a Thesis (Ph.D.)--University of South Carolina, 2021.
506 $a This item must not be sold to any third party vendors.
520 $a Heavy metal contamination is a growing concern throughout the world, particularly as industrial and urban activities have increased. Inadequate water and wastewater treatment, coupled with increased industrial activity, have led to increased heavy metal contamination in rivers, lakes, and other water sources in developing countries. To address these concerns, a significant amount of research has been conducted on various novel adsorbents to evaluate their ability to remove heavy metals. Thus, in this study, MIL-100(Fe) and MIL-101(Cr) are fabricated and investigated to determine their ability to remove copper (Cu2+), cadmium (Cd2+), and lead (Pb2+) from aqueous solution. The experimental data fit most closely to the Freundlich model, followed closely by the Linear isotherm model. However, the values for the Freundlich parameter n were close to 1, which suggests that the adsorption followed the Linear isotherm model. The KLIN coefficient [(mg/g)/(mg/L)] for the Linear isotherm model was the largest for Cu2+, followed by Cd2+ and Pb2+. MIL-100(Fe) and MIL-101(Cr) exhibited fast adsorption kinetics, achieving equilibrium in approximately 0.5 hours. Electrostatic interactions were determined to be the dominant adsorption mechanism for the removal of Cu2+, Cd2+, and Pb2+ by MIL-100(Fe) and MIL-101(Cr), which is consistent with similar adsorption studies. This study shows that MIL-100(Fe) and MIL-101(Cr) are effective adsorbents for the removal of heavy metals from aqueous solution.
590 $a School code: 0202.
650 4 $a Environmental engineering. $3 548583
650 4 $a Inorganic chemistry. $3 3173556
650 4 $a Water resources management. $3 794747
653 $a Adsorption
653 $a Contaminants of emerging concern
653 $a Heavy metals
653 $a Metal organic frameworks
653 $a Water treatment
690 $a 0775
690 $a 0488
690 $a 0595
690 $a 0474
710 2 $a University of South Carolina. $b Civil Engineering. $3 1020945
773 0 $t Dissertations Abstracts International $g 83-03B.
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791 $a Ph.D.
792 $a 2021
793 $a English
856 4 0 $u https://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=28411440