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Chemical Studies of Caribbean Marine...

Vansach, Tifanie.

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Chemical Studies of Caribbean Marine Organisms.

Record Type:	Electronic resources : Monograph/item
Title/Author:	Chemical Studies of Caribbean Marine Organisms./
Author:	Vansach, Tifanie.
Published:	Ann Arbor : ProQuest Dissertations & Theses, : 2019,
Description:	176 p.
Notes:	Source: Dissertations Abstracts International, Volume: 80-12, Section: B.
Contained By:	Dissertations Abstracts International80-12B.
Subject:	Chemical Oceanography. -
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=13863278
ISBN:	9781392275078

Chemical Studies of Caribbean Marine Organisms.
Vansach, Tifanie.

Chemical Studies of Caribbean Marine Organisms. - Ann Arbor : ProQuest Dissertations & Theses, 2019 - 176 p.

Source: Dissertations Abstracts International, Volume: 80-12, Section: B.

Thesis (Ph.D.)--Florida Atlantic University, 2019.

This item is not available from ProQuest Dissertations & Theses.

The projects described in this dissertation concentrated on investigating Caribbean species for qualitative and quantitative chemical differences. Chapter one includes a brief update on the status of natural products as drugs, a discussion of the biodiversity of Caribbean marine organisms as well as a discussion about the chemistry of algae and sponges.In chapter two, an experiment to test for possible effects of warmer, more acidic water and how that will impact coral reef organisms was conducted. Six common Caribbean coral reef sponge species were grown in seawater for 24 days ranging from values experienced at summer-maxima (temperature = 28 °C; pH = 8.1) to those predicted for the year 2100 (T = 31 °C; pH = 7.8). For each species, attachment rates, growth, and survival were similar between temperature and pH levels. Only two metabolite concentrations varied significantly between treatments but were similar to baseline levels.In chapter three, a chemical survey of Florida Keys algae was performed using MeOH extraction and HP-20 SPE with varying Me2CO:H2O solutions. 1H NMR spectra were collected for each fraction and analyzed for interesting signals. A Laurencia sp. was extracted and found to contain the known compound isodactylyne (61) with the structure determined using spectroscopic analyses.In chapter four, a Laurencia obtusa specimen was investigated to determine the compound causing oxygenated signals between 4.50 - 4.80 ppm in the 1H NMR spectra observed in chapter three. A large scale extraction and fractionation was performed and the compound was determined to be 1-O-palmitoyl-2-O-myristoyl-3-O-(6-sulfo-α-D-quinovo-pyranosyl)-glycerol (63).In chapter five, the isolation and structural elucidation of a new compound, furocaespitanenone (64) and two known compounds (10R)- and (10S)-10-O-methyl-furocaespitanelactol 65 and 66, from a Laurencia sp. collected off of the Florida Keys using MeOH extraction and HP-20 column chromatography is described. A potential biosynthesis of 64 from furocaepsitane (68) is proposed.

ISBN: 9781392275078Subjects--Topical Terms:

1674678
Chemical Oceanography.
Subjects--Index Terms:

Caribbean sponges

Chemical Studies of Caribbean Marine Organisms.
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500 $a Source: Dissertations Abstracts International, Volume: 80-12, Section: B.
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502 $a Thesis (Ph.D.)--Florida Atlantic University, 2019.
506 $a This item is not available from ProQuest Dissertations & Theses.
506 $a This item must not be sold to any third party vendors.
520 $a The projects described in this dissertation concentrated on investigating Caribbean species for qualitative and quantitative chemical differences. Chapter one includes a brief update on the status of natural products as drugs, a discussion of the biodiversity of Caribbean marine organisms as well as a discussion about the chemistry of algae and sponges.In chapter two, an experiment to test for possible effects of warmer, more acidic water and how that will impact coral reef organisms was conducted. Six common Caribbean coral reef sponge species were grown in seawater for 24 days ranging from values experienced at summer-maxima (temperature = 28 °C; pH = 8.1) to those predicted for the year 2100 (T = 31 °C; pH = 7.8). For each species, attachment rates, growth, and survival were similar between temperature and pH levels. Only two metabolite concentrations varied significantly between treatments but were similar to baseline levels.In chapter three, a chemical survey of Florida Keys algae was performed using MeOH extraction and HP-20 SPE with varying Me2CO:H2O solutions. 1H NMR spectra were collected for each fraction and analyzed for interesting signals. A Laurencia sp. was extracted and found to contain the known compound isodactylyne (61) with the structure determined using spectroscopic analyses.In chapter four, a Laurencia obtusa specimen was investigated to determine the compound causing oxygenated signals between 4.50 - 4.80 ppm in the 1H NMR spectra observed in chapter three. A large scale extraction and fractionation was performed and the compound was determined to be 1-O-palmitoyl-2-O-myristoyl-3-O-(6-sulfo-α-D-quinovo-pyranosyl)-glycerol (63).In chapter five, the isolation and structural elucidation of a new compound, furocaespitanenone (64) and two known compounds (10R)- and (10S)-10-O-methyl-furocaespitanelactol 65 and 66, from a Laurencia sp. collected off of the Florida Keys using MeOH extraction and HP-20 column chromatography is described. A potential biosynthesis of 64 from furocaepsitane (68) is proposed.
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