東華大學圖書館 |

Language: English

Help

回圖書館首頁

手機版館藏查詢

Back

Switch To: Labeled | MARC Mode | ISBD

Study of new ternary rare-earth inte...

Freccero, Riccardo.

Linked to FindBook

Google Book

Amazon

博客來

Study of new ternary rare-earth intermetallic germanides with polar covalent bonding = beyond the Zintl picture /

Record Type:	Electronic resources : Monograph/item
Title/Author:	Study of new ternary rare-earth intermetallic germanides with polar covalent bonding/ by Riccardo Freccero.
Reminder of title:	beyond the Zintl picture /
Author:	Freccero, Riccardo.
Published:	Cham :Springer International Publishing : : 2020.,
Description:	xxi, 221 p. :ill., digital ;24 cm.
[NT 15003449]:	Introduction -- Experimental Methods -- Theoretical Methods -- The R2MGe6 (R = rare earth metal; M = another metal) Compounds: An Experimental and Theoretical Study on Their Synthesis, Crystal Structure and Chemical Bonding -- On the Existence, Crystal Structure and Physical Properties of R2Pd3Ge5 (R = rare earth metal) Intermetallic Germanides -- Lu5Pd4Ge8, Lu3Pd4Ge4 and Yb2PdGe3: Three More Germanides among Polar Intermetallics.
Contained By:	Springer Nature eBook
Subject:	Germanides. -
Online resource:	https://doi.org/10.1007/978-3-030-58992-9
ISBN:	9783030589929

Study of new ternary rare-earth intermetallic germanides with polar covalent bonding = beyond the Zintl picture /
Freccero, Riccardo.

Study of new ternary rare-earth intermetallic germanides with polar covalent bondingbeyond the Zintl picture /[electronic resource] :by Riccardo Freccero. - Cham :Springer International Publishing :2020. - xxi, 221 p. :ill., digital ;24 cm. - Springer theses,2190-5053. - Springer theses..

Introduction -- Experimental Methods -- Theoretical Methods -- The R2MGe6 (R = rare earth metal; M = another metal) Compounds: An Experimental and Theoretical Study on Their Synthesis, Crystal Structure and Chemical Bonding -- On the Existence, Crystal Structure and Physical Properties of R2Pd3Ge5 (R = rare earth metal) Intermetallic Germanides -- Lu5Pd4Ge8, Lu3Pd4Ge4 and Yb2PdGe3: Three More Germanides among Polar Intermetallics.

The thesis focuses on the syntheses, structural characterizations and chemical bonding analyses for several ternary R-M-Ge (R = rare earth metal; M = another metal) intermetallics. The challenges in understanding the main interactions governing the chemistry of these compounds, which lead to our inability to predict their formation, structure and properties, are what provided the motivation for this study. In particular, the R2MGe6 (M = Li, Mg, Al, Cu, Zn, Pd, Ag), R4MGe10-x (M = Li, Mg), R2Pd3Ge5, Lu5Pd4Ge8, Lu3Pd4Ge4 and Yb2PdGe3 phases were synthesized and structurally characterized. Much effort was put into the stabilization of metastable phases, employing the innovative metal flux method, and into the accurate structure solution of twinned crystals. Cutting-edge position-space chemical bonding techniques were combined with new methodologies conceived to correctly describe the Ge-M, Ge-La and also La-M polar-covalent interactions for the La2MGe6 (M = Li, Mg, Al, Cu, Zn, Pd, Ag) series. The present results constitute a step forward in our comprehension of ternary germanide chemistry as well as providing a good playground for further investigations.

ISBN: 9783030589929

Standard No.: 10.1007/978-3-030-58992-9doiSubjects--Topical Terms:

3527459
Germanides.

LC Class. No.: QD412.G5 / F74 2020

Dewey Class. No.: 547.05684

Study of new ternary rare-earth intermetallic germanides with polar covalent bonding = beyond the Zintl picture /
LDR:02699nmm a2200337 a 4500 001 2256835
003 DE-He213
005 20210225135930.0
006 m d
007 cr nn 008maaau
008 220420s2020 sz s 0 eng d
020 $a 9783030589929 $q (electronic bk.)
020 $a 9783030589912 $q (paper)
024 7 $a 10.1007/978-3-030-58992-9 $2 doi
035 $a 978-3-030-58992-9
040 $a GP $c GP
041 0 $a eng
050 4 $a QD412.G5 $b F74 2020
072 7 $a TGM $2 bicssc
072 7 $a TEC021000 $2 bisacsh
072 7 $a TGM $2 thema
082 0 4 $a 547.05684 $2 23
090 $a QD412.G5 $b F851 2020
100 1 $a Freccero, Riccardo. $3 3527458
245 1 0 $a Study of new ternary rare-earth intermetallic germanides with polar covalent bonding $h [electronic resource] : $b beyond the Zintl picture / $c by Riccardo Freccero.
260 $a Cham : $b Springer International Publishing : $b Imprint: Springer, $c 2020.
300 $a xxi, 221 p. : $b ill., digital ; $c 24 cm.
490 1 $a Springer theses, $x 2190-5053
505 0 $a Introduction -- Experimental Methods -- Theoretical Methods -- The R2MGe6 (R = rare earth metal; M = another metal) Compounds: An Experimental and Theoretical Study on Their Synthesis, Crystal Structure and Chemical Bonding -- On the Existence, Crystal Structure and Physical Properties of R2Pd3Ge5 (R = rare earth metal) Intermetallic Germanides -- Lu5Pd4Ge8, Lu3Pd4Ge4 and Yb2PdGe3: Three More Germanides among Polar Intermetallics.
520 $a The thesis focuses on the syntheses, structural characterizations and chemical bonding analyses for several ternary R-M-Ge (R = rare earth metal; M = another metal) intermetallics. The challenges in understanding the main interactions governing the chemistry of these compounds, which lead to our inability to predict their formation, structure and properties, are what provided the motivation for this study. In particular, the R2MGe6 (M = Li, Mg, Al, Cu, Zn, Pd, Ag), R4MGe10-x (M = Li, Mg), R2Pd3Ge5, Lu5Pd4Ge8, Lu3Pd4Ge4 and Yb2PdGe3 phases were synthesized and structurally characterized. Much effort was put into the stabilization of metastable phases, employing the innovative metal flux method, and into the accurate structure solution of twinned crystals. Cutting-edge position-space chemical bonding techniques were combined with new methodologies conceived to correctly describe the Ge-M, Ge-La and also La-M polar-covalent interactions for the La2MGe6 (M = Li, Mg, Al, Cu, Zn, Pd, Ag) series. The present results constitute a step forward in our comprehension of ternary germanide chemistry as well as providing a good playground for further investigations.
650 0 $a Germanides. $3 3527459
650 1 4 $a Materials Science, general. $3 927806
650 2 4 $a Characterization and Evaluation of Materials. $3 890988
650 2 4 $a Physical Chemistry. $3 890828
650 2 4 $a Structural Materials. $3 898417
650 2 4 $a Chemistry/Food Science, general. $3 894122
710 2 $a SpringerLink (Online service) $3 836513
773 0 $t Springer Nature eBook
830 0 $a Springer theses. $3 1314442
856 4 0 $u https://doi.org/10.1007/978-3-030-58992-9
950 $a Chemistry and Materials Science (SpringerNature-11644)