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Angle resolved photoemission spectro...
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Sunko, Veronika.
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Angle resolved photoemission spectroscopy of delafossite metals
Record Type:
Electronic resources : Monograph/item
Title/Author:
Angle resolved photoemission spectroscopy of delafossite metals/ by Veronika Sunko.
Author:
Sunko, Veronika.
Published:
Cham :Springer International Publishing : : 2019.,
Description:
xvii, 198 p. :ill. (some col.), digital ;24 cm.
[NT 15003449]:
Introduction -- Angle Resolved Photoemission -- Theory and Models -- Bulk States in PtCoO2 and PdCoO2 -- Coupling of Metallic and Mott-insulating states in PdCrO2 -- Rashba-like Spin-Split Surface States -- Conclusions and Outlook -- Appendices.
Contained By:
Springer eBooks
Subject:
Photoelectron spectroscopy. -
Online resource:
https://doi.org/10.1007/978-3-030-31087-5
ISBN:
9783030310875
Angle resolved photoemission spectroscopy of delafossite metals
Sunko, Veronika.
Angle resolved photoemission spectroscopy of delafossite metals
[electronic resource] /by Veronika Sunko. - Cham :Springer International Publishing :2019. - xvii, 198 p. :ill. (some col.), digital ;24 cm. - Springer theses,2190-5053. - Springer theses..
Introduction -- Angle Resolved Photoemission -- Theory and Models -- Bulk States in PtCoO2 and PdCoO2 -- Coupling of Metallic and Mott-insulating states in PdCrO2 -- Rashba-like Spin-Split Surface States -- Conclusions and Outlook -- Appendices.
This thesis describes the results of angle resolved photoemission spectroscopy experiments on delafossite oxide metals, and theoretical work explaining these observations. The study was motivated by the extraordinarily high conductivity of the non-magnetic delafossites PdCoO2 and PtCoO2, the measurement of whose electronic structure is reported and discussed. Two unexpected effects were observed in the course of the investigation; each is described and analysed in detail. Firstly, a previously unrecognised type of spectroscopic signal, allowing the non-magnetic probe of photoemission to become sensitive to spin-spin correlations, was observed in the antiferromagnetic PdCrO2. Its origin was identified as the Kondo-like coupling of itinerant and Mott insulating electrons. Furthermore, surface states exhibiting an unusually large Rashba-like spin-splitting were observed on the transition metal terminated surfaces of delafossites. The large inversion symmetry breaking energy scale, a consequence of the unusual structure of the surface layer, is identified as the origin of the effect.
ISBN: 9783030310875
Standard No.: 10.1007/978-3-030-31087-5doiSubjects--Topical Terms:
697357
Photoelectron spectroscopy.
LC Class. No.: QC454.P48 / S865 2019
Dewey Class. No.: 530.41
Angle resolved photoemission spectroscopy of delafossite metals
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Introduction -- Angle Resolved Photoemission -- Theory and Models -- Bulk States in PtCoO2 and PdCoO2 -- Coupling of Metallic and Mott-insulating states in PdCrO2 -- Rashba-like Spin-Split Surface States -- Conclusions and Outlook -- Appendices.
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This thesis describes the results of angle resolved photoemission spectroscopy experiments on delafossite oxide metals, and theoretical work explaining these observations. The study was motivated by the extraordinarily high conductivity of the non-magnetic delafossites PdCoO2 and PtCoO2, the measurement of whose electronic structure is reported and discussed. Two unexpected effects were observed in the course of the investigation; each is described and analysed in detail. Firstly, a previously unrecognised type of spectroscopic signal, allowing the non-magnetic probe of photoemission to become sensitive to spin-spin correlations, was observed in the antiferromagnetic PdCrO2. Its origin was identified as the Kondo-like coupling of itinerant and Mott insulating electrons. Furthermore, surface states exhibiting an unusually large Rashba-like spin-splitting were observed on the transition metal terminated surfaces of delafossites. The large inversion symmetry breaking energy scale, a consequence of the unusual structure of the surface layer, is identified as the origin of the effect.
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Photoelectron spectroscopy.
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Surfaces and Interfaces, Thin Films.
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Physics and Astronomy (Springer-11651)
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EB QC454.P48 S865 2019
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