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Organic molecular cages as templates...

McCaffrey, Ryan.

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Organic molecular cages as templates for the synthesis of metallic nanoparticles: From stabilization to application and assembly.

Record Type:	Electronic resources : Monograph/item
Title/Author:	Organic molecular cages as templates for the synthesis of metallic nanoparticles: From stabilization to application and assembly./
Author:	McCaffrey, Ryan.
Published:	Ann Arbor : ProQuest Dissertations & Theses, : 2016,
Description:	141 p.
Notes:	Source: Dissertation Abstracts International, Volume: 78-03(E), Section: B.
Contained By:	Dissertation Abstracts International78-03B(E).
Subject:	Chemistry. -
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=10151133
ISBN:	9781369058970

Organic molecular cages as templates for the synthesis of metallic nanoparticles: From stabilization to application and assembly.
McCaffrey, Ryan.

Organic molecular cages as templates for the synthesis of metallic nanoparticles: From stabilization to application and assembly. - Ann Arbor : ProQuest Dissertations & Theses, 2016 - 141 p.

Source: Dissertation Abstracts International, Volume: 78-03(E), Section: B.

Thesis (Ph.D.)--University of Colorado at Boulder, 2016.

Shape-persistent 3-D covalent organic polyhedrons (COPs) with well-defined intrinsic cavities have been well studied in materials chemistry due to their applications in host-guest chemistry, chemical sensing and gas adsorption and separation. However, the use of 3-D COPs as endo-templates for the synthesis of metallic nanoparticles has not been intensely explored. The purpose of the work described within this thesis is to answer the following questions: Can discrete, purely organic hollow molecular structures be designed in such a way as to facilitate the size-controlled synthesis of metallic nanoparticles? What are the applications of such organic-inorganic hybrid structures? Is it feasible for such structures to be used as the basic repeat units for further chemical assembling into more complex architectures?

ISBN: 9781369058970Subjects--Topical Terms:

516420
Chemistry.

Organic molecular cages as templates for the synthesis of metallic nanoparticles: From stabilization to application and assembly.
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520 $a Shape-persistent 3-D covalent organic polyhedrons (COPs) with well-defined intrinsic cavities have been well studied in materials chemistry due to their applications in host-guest chemistry, chemical sensing and gas adsorption and separation. However, the use of 3-D COPs as endo-templates for the synthesis of metallic nanoparticles has not been intensely explored. The purpose of the work described within this thesis is to answer the following questions: Can discrete, purely organic hollow molecular structures be designed in such a way as to facilitate the size-controlled synthesis of metallic nanoparticles? What are the applications of such organic-inorganic hybrid structures? Is it feasible for such structures to be used as the basic repeat units for further chemical assembling into more complex architectures?
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