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Alignment and Load Transfer in Carbo...

Severino, Joseph Vincent.

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Alignment and Load Transfer in Carbon Nanotube and Dicyclopentadiene Composites.

Record Type:	Electronic resources : Monograph/item
Title/Author:	Alignment and Load Transfer in Carbon Nanotube and Dicyclopentadiene Composites./
Author:	Severino, Joseph Vincent.
Description:	253 p.
Notes:	Source: Dissertation Abstracts International, Volume: 77-02(E), Section: B.
Contained By:	Dissertation Abstracts International77-02B(E).
Subject:	Materials science. -
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3724900
ISBN:	9781339086699

Alignment and Load Transfer in Carbon Nanotube and Dicyclopentadiene Composites.
Severino, Joseph Vincent.

Alignment and Load Transfer in Carbon Nanotube and Dicyclopentadiene Composites. - 253 p.

Source: Dissertation Abstracts International, Volume: 77-02(E), Section: B.

Thesis (Ph.D.)--University of California, Los Angeles, 2015.

Individual carbon nanotubes (CNTs) are the strongest materials available but their macroscopic assemblies are weak. This work establishes a new thermosetting dicyclopentadiene (DCPD) and CNT composite that increases the strength of CNT assemblies. These high volume fraction and void free structures constitute advanced materials that could one day replace traditional composite systems. To further the understanding of physical interactions between polymer and CNTs, a novel "capstan" load transfer mechanism is also introduced. Self-supporting assemblies of interconnected carbon nanotubes were stretched, twisted and compressed to fashion composites by the infusion and polymerization of low viscosity DCPD based monomeric resins. The properties of the CNTs, polymer and composite were characterized with thermal gravimetric analysis (TGA), dynamic mechanical analysis (DMA) and Raman spectroscopy. The microstructure was analyzed by wide angle X-ray scattering (WAXS), scanning electron microscopy (SEM) and transmission electron microscopy (TEM).

ISBN: 9781339086699Subjects--Topical Terms:

543314
Materials science.

Alignment and Load Transfer in Carbon Nanotube and Dicyclopentadiene Composites.
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020 $a 9781339086699
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100 1 $a Severino, Joseph Vincent. $3 3193102
245 1 0 $a Alignment and Load Transfer in Carbon Nanotube and Dicyclopentadiene Composites.
300 $a 253 p.
500 $a Source: Dissertation Abstracts International, Volume: 77-02(E), Section: B.
500 $a Adviser: Jenn-Ming Yang.
502 $a Thesis (Ph.D.)--University of California, Los Angeles, 2015.
520 $a Individual carbon nanotubes (CNTs) are the strongest materials available but their macroscopic assemblies are weak. This work establishes a new thermosetting dicyclopentadiene (DCPD) and CNT composite that increases the strength of CNT assemblies. These high volume fraction and void free structures constitute advanced materials that could one day replace traditional composite systems. To further the understanding of physical interactions between polymer and CNTs, a novel "capstan" load transfer mechanism is also introduced. Self-supporting assemblies of interconnected carbon nanotubes were stretched, twisted and compressed to fashion composites by the infusion and polymerization of low viscosity DCPD based monomeric resins. The properties of the CNTs, polymer and composite were characterized with thermal gravimetric analysis (TGA), dynamic mechanical analysis (DMA) and Raman spectroscopy. The microstructure was analyzed by wide angle X-ray scattering (WAXS), scanning electron microscopy (SEM) and transmission electron microscopy (TEM).
520 $a Sheets were drawn at 15 m/min from a growth furnace to impart alignment then stretched to further modify alignment. The mechanical properties were determined in five orientations with respect to the growth direction. The strength was nearly three times higher along this growth direction than it was perpendicular, and modulus was nearly six times higher. Transverse stretching achieved 1.5 times the elongation but alignment was inferior due to CNT kinking that prevented alignment and consolidation.
520 $a Composites yarns and sheets were investigated for the mechanical properties, microstructure and load transfer. The DCPD resin was found to wet the CNTs and lubricated deformation. This reduced loads during processing, and curing solidified the aligned and consolidated structure. The stretched and twisted composite yarns increased the failure stress 51%. In aligned composite sheet, the failure stress increased 200%. The increased stresses were attributed to load transfer by a capstan mechanism that utilized the kinked CNTs that formed as a result of stretching. This mechanism reflects the tortuous structure of real CNT assemblies.
590 $a School code: 0031.
650 4 $a Materials science. $3 543314
650 4 $a Nanoscience. $3 587832
650 4 $a Nanotechnology. $3 526235
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710 2 $a University of California, Los Angeles. $b Materials Science and Engineering. $3 2105028
773 0 $t Dissertation Abstracts International $g 77-02B(E).
790 $a 0031
791 $a Ph.D.
792 $a 2015
793 $a English
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3724900