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Understanding of chemical reactions ...

Radepont, Marie.

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Understanding of chemical reactions involved in pigment discoloration, in particular in mercury sulfide (HgS) blackening.

Record Type:	Language materials, printed : Monograph/item
Title/Author:	Understanding of chemical reactions involved in pigment discoloration, in particular in mercury sulfide (HgS) blackening./
Author:	Radepont, Marie.
Description:	233 p.
Notes:	Source: Dissertation Abstracts International, Volume: 74-12(E), Section: B.
Contained By:	Dissertation Abstracts International74-12B(E).
Subject:	Chemistry, Analytical. -
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3574018
ISBN:	9781303460043

Understanding of chemical reactions involved in pigment discoloration, in particular in mercury sulfide (HgS) blackening.
Radepont, Marie.

Understanding of chemical reactions involved in pigment discoloration, in particular in mercury sulfide (HgS) blackening. - 233 p.

Source: Dissertation Abstracts International, Volume: 74-12(E), Section: B.

Thesis (Ph.D.)--Universiteit Antwerpen (Belgium), 2013.

Pigments colour can sometimes evolve, unexpectedly, from the painter's or curator's point of view. The most common degradation of red mercury sulfide (alpha-HgS), used in a cinnabar natural form or in a vermilion synthetic form, is turning into black or silver-gray. This phenomenon is rather capricious and does not happen systematically. Since Antiquity, cinnabar was often used in paintings, even if it was known to suffer from degradation under the influence of sunlight.

ISBN: 9781303460043Subjects--Topical Terms:

586156
Chemistry, Analytical.

Understanding of chemical reactions involved in pigment discoloration, in particular in mercury sulfide (HgS) blackening.
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005 20140701144857.5
008 150210s2013 ||||||||||||||||| ||eng d
020 $a 9781303460043
035 $a (MiAaPQ)AAI3574018
035 $a AAI3574018
040 $a MiAaPQ $c MiAaPQ
100 1 $a Radepont, Marie. $3 2096777
245 1 0 $a Understanding of chemical reactions involved in pigment discoloration, in particular in mercury sulfide (HgS) blackening.
300 $a 233 p.
500 $a Source: Dissertation Abstracts International, Volume: 74-12(E), Section: B.
500 $a Advisers: Koen Janssens; Marine Cotte.
502 $a Thesis (Ph.D.)--Universiteit Antwerpen (Belgium), 2013.
520 $a Pigments colour can sometimes evolve, unexpectedly, from the painter's or curator's point of view. The most common degradation of red mercury sulfide (alpha-HgS), used in a cinnabar natural form or in a vermilion synthetic form, is turning into black or silver-gray. This phenomenon is rather capricious and does not happen systematically. Since Antiquity, cinnabar was often used in paintings, even if it was known to suffer from degradation under the influence of sunlight.
520 $a Analyses of original works of art presenting mercury sulfide in their pictorial layers allowed identifying different degradation compounds, such as calomel (Hg2Cl2) and different polymorphous phases of Hg3S2Cl2. Furthermore, artificial ageing experiments were used to reproduce the formation of some of these products on model samples and confirm light and chlorine as two necessary parameters to induce the presence of these alteration products. Pourbaix diagrams and simulations obtained from thermodynamics calculation appeared to be consistent with the evolution of the composition of alpha-HgS model samples during artificial ageing experiments. The chemical characterization of the alteration products was rather challenging mainly because of the micrometric size of the alteration (multi-)layers. Beyond the different analytical techniques available, synchrotron-based micro X-ray diffraction, micro X-ray fluorescence and micro X-ray absorption spectroscopy proved to be very helpful for the identification and localization of both original and altered compounds.
520 $a These researches confirmed preliminary hypothesis on factors influencing the alteration of mercury sulfide and explain the conditions in which these degradations occur in order to avoid them in the future.
590 $a School code: 1513.
650 4 $a Chemistry, Analytical. $3 586156
650 4 $a Chemistry, Inorganic. $3 517253
690 $a 0486
690 $a 0488
710 2 $a Universiteit Antwerpen (Belgium). $b Chemistry. $3 2096778
773 0 $t Dissertation Abstracts International $g 74-12B(E).
790 $a 1513
791 $a Ph.D.
792 $a 2013
793 $a English
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3574018