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Infrared studies of hydrogen bonding...

Robertson, William Henry.

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Infrared studies of hydrogen bonding in the presence of negative ions.

Record Type:	Electronic resources : Monograph/item
Title/Author:	Infrared studies of hydrogen bonding in the presence of negative ions./
Author:	Robertson, William Henry.
Description:	228 p.
Notes:	Source: Dissertation Abstracts International, Volume: 64-10, Section: B, page: 4963.
Contained By:	Dissertation Abstracts International64-10B.
Subject:	Chemistry, Physical. -
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3109453

Infrared studies of hydrogen bonding in the presence of negative ions.
Robertson, William Henry.

Infrared studies of hydrogen bonding in the presence of negative ions. - 228 p.

Source: Dissertation Abstracts International, Volume: 64-10, Section: B, page: 4963.

Thesis (Ph.D.)--Yale University, 2003.

This thesis is an investigation of the hydration structures formed in the immediate vicinity of anions. Infrared spectroscopy of mass-selected anion hydrate clusters was employed to strip away the contribution of the bulk solvent so as to focus on the molecular details of the highly distorted molecules near the anion. The anionic H-bond was studied by comparing the spectra of several binary anion-water complexes to assess the relative contributions of proton transfer versus electrostatic interactions and the effects of charge delocalization both within molecular anions and away onto competing solvent molecules. These concepts were then exploited in the exploration of water network formation on molecular anions in the higher hydrates. This work provides definitive spectroscopic evidence for hydration shell closure in OH -·(H2O)3 and F-·(H 2O)4 clusters.Subjects--Topical Terms:

560527
Chemistry, Physical.

Infrared studies of hydrogen bonding in the presence of negative ions.
LDR:01732nmm 2200265 4500 001 1864482
005 20041216132050.5
008 130614s2003 eng d
035 $a (UnM)AAI3109453
035 $a AAI3109453
040 $a UnM $c UnM
100 1 $a Robertson, William Henry. $3 1951972
245 1 0 $a Infrared studies of hydrogen bonding in the presence of negative ions.
300 $a 228 p.
500 $a Source: Dissertation Abstracts International, Volume: 64-10, Section: B, page: 4963.
500 $a Director: Mark Albert Johnson.
502 $a Thesis (Ph.D.)--Yale University, 2003.
520 $a This thesis is an investigation of the hydration structures formed in the immediate vicinity of anions. Infrared spectroscopy of mass-selected anion hydrate clusters was employed to strip away the contribution of the bulk solvent so as to focus on the molecular details of the highly distorted molecules near the anion. The anionic H-bond was studied by comparing the spectra of several binary anion-water complexes to assess the relative contributions of proton transfer versus electrostatic interactions and the effects of charge delocalization both within molecular anions and away onto competing solvent molecules. These concepts were then exploited in the exploration of water network formation on molecular anions in the higher hydrates. This work provides definitive spectroscopic evidence for hydration shell closure in OH -·(H2O)3 and F-·(H 2O)4 clusters.
590 $a School code: 0265.
650 4 $a Chemistry, Physical. $3 560527
650 4 $a Physics, Molecular. $3 1018648
690 $a 0494
690 $a 0609
710 2 0 $a Yale University. $3 515640
773 0 $t Dissertation Abstracts International $g 64-10B.
790 1 0 $a Johnson, Mark Albert, $e advisor
790 $a 0265
791 $a Ph.D.
792 $a 2003
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3109453