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Chemical analysis with electrogenera...
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Forry, Samuel P.
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Chemical analysis with electrogenerated chemiluminescence.
紀錄類型:
書目-電子資源 : Monograph/item
正題名/作者:
Chemical analysis with electrogenerated chemiluminescence./
作者:
Forry, Samuel P.
面頁冊數:
128 p.
附註:
Source: Dissertation Abstracts International, Volume: 64-11, Section: B, page: 5492.
Contained By:
Dissertation Abstracts International64-11B.
標題:
Chemistry, Analytical. -
電子資源:
http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3112006
Chemical analysis with electrogenerated chemiluminescence.
Forry, Samuel P.
Chemical analysis with electrogenerated chemiluminescence.
- 128 p.
Source: Dissertation Abstracts International, Volume: 64-11, Section: B, page: 5492.
Thesis (Ph.D.)--The University of North Carolina at Chapel Hill, 2003.
Electrogenerated chemiluminescence is the production of excited states through reactions between electrochemically generated intermediates. It can be quite sensitive and useful in chemical analysis. Chapter 1 describes the fundamentals of organic ECL and with examples from the most common organic ECL systems. In Chapter 2, these fundamentals are utilized to allow sensitive and selective ECL detection of some polyaromatic hydrocarbons following liquid chromatographic separation. A derivatization scheme is presented which allows ECL detection of primary amines. Chapter 3 investigates the kinetics of an oxidative-reductive system. This system allows ECL detection in aqueous solutions, but is found to exhibit a slow kinetics. In Chapter 4, detection is demonstrated in a microfluidic device. A method is demonstrated which allows electrochemical measurements in the presence of an electric field without need for a decoupler. Fast scan cyclic voltammetry and ECL detection are demonstrated following electrophoretic separations. In Chapter 5, an approach is presented which facilitates the ECL simulations. Software designed for simulations of electrochemical responses can be used to simulate ECL emission arising from complex mechanisms.Subjects--Topical Terms:
586156
Chemistry, Analytical.
Chemical analysis with electrogenerated chemiluminescence.
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Source: Dissertation Abstracts International, Volume: 64-11, Section: B, page: 5492.
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Electrogenerated chemiluminescence is the production of excited states through reactions between electrochemically generated intermediates. It can be quite sensitive and useful in chemical analysis. Chapter 1 describes the fundamentals of organic ECL and with examples from the most common organic ECL systems. In Chapter 2, these fundamentals are utilized to allow sensitive and selective ECL detection of some polyaromatic hydrocarbons following liquid chromatographic separation. A derivatization scheme is presented which allows ECL detection of primary amines. Chapter 3 investigates the kinetics of an oxidative-reductive system. This system allows ECL detection in aqueous solutions, but is found to exhibit a slow kinetics. In Chapter 4, detection is demonstrated in a microfluidic device. A method is demonstrated which allows electrochemical measurements in the presence of an electric field without need for a decoupler. Fast scan cyclic voltammetry and ECL detection are demonstrated following electrophoretic separations. In Chapter 5, an approach is presented which facilitates the ECL simulations. Software designed for simulations of electrochemical responses can be used to simulate ECL emission arising from complex mechanisms.
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http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3112006
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