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Anisotropic lattice thermal diffusiv...

Harrell, Michael Damian.

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Anisotropic lattice thermal diffusivity in olivines and pyroxenes to high temperatures.

Record Type:	Electronic resources : Monograph/item
Title/Author:	Anisotropic lattice thermal diffusivity in olivines and pyroxenes to high temperatures./
Author:	Harrell, Michael Damian.
Description:	207 p.
Notes:	Source: Dissertation Abstracts International, Volume: 63-05, Section: B, page: 2269.
Contained By:	Dissertation Abstracts International63-05B.
Subject:	Mineralogy. -
Online resource:	http://pqdd.sinica.edu.tw/twdaoeng/servlet/advanced?query=3053509
ISBN:	0493682368

Anisotropic lattice thermal diffusivity in olivines and pyroxenes to high temperatures.
Harrell, Michael Damian.

Anisotropic lattice thermal diffusivity in olivines and pyroxenes to high temperatures. - 207 p.

Source: Dissertation Abstracts International, Volume: 63-05, Section: B, page: 2269.

Thesis (Ph.D.)--University of Washington, 2002.

The anisotropic lattice thermal diffusivity of three olivines (Fo 0, Fo78, and Fo91), one orthopyroxene (En 91), and one clinopyroxene (Di72He9Jd3Cr 3Ts12) have been measured via impulsive stimulated light scattering, permitting the calculation of their lattice thermal diffusivity tensors to high temperatures. For Fo0 olivine, measurements extend from room temperature to 600°C, for Fo78 to 900°C, and for Fo91 to 1000°C, all in steps of 100°C. The orthopyroxene also was taken in steps to 1000°C, while the clinopyroxene was measured at room temperature. A limited set of room-temperature measurements to 5 GPa on a fourth olivine (Fo89) is also included. Diffusivities have been combined with calculations of density and specific heat to determine the lattice thermal conductivity tensors. An earlier theory that explains the observed behavior in terms of a positive lower bound on the phonon mean free path is discussed, and the data are used to constrain a model of thermal conductivity at high temperature. The relative contributions of optic and acoustic modes are evaluated from analysis of published dispersion curves. Five conclusions are reached: First, the anisotropy of lattice thermal conductivity remains essentially unchanged over the observed range of temperatures, indicating that anisotropy remains significant under upper-mantle conditions, and, in regions displaying preferred alignment, may account for observed lateral variations in the geotherm. Second, thermal conductivity departs significantly from earlier predictions of its temperature dependence; this may be understood in terms of a phonon mean free path that cannot diminish below 1.75 times the mean interatomic spacing. Third, for olivine, the optic modes have group velocities that are approximately one-third those of the acoustic modes, and do not dominate lattice conduction despite their greater number. Fourth, impurity scattering is significant along the olivine Fe-Mg solid solution series, but is not appreciable near the endpoints and therefore likely does not play a major role in the upper mantle. Fifth, the historic underestimation of lattice thermal conductivity at temperature has led to an overestimation of radiative conductivity; radiative transport, although significant, plays an even smaller role in the upper mantle than has heretofore been assumed.

ISBN: 0493682368Subjects--Topical Terms:

516743
Mineralogy.

Anisotropic lattice thermal diffusivity in olivines and pyroxenes to high temperatures.
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100 1 $a Harrell, Michael Damian. $3 1944556
245 1 0 $a Anisotropic lattice thermal diffusivity in olivines and pyroxenes to high temperatures.
300 $a 207 p.
500 $a Source: Dissertation Abstracts International, Volume: 63-05, Section: B, page: 2269.
500 $a Chair: John Michael Brown.
502 $a Thesis (Ph.D.)--University of Washington, 2002.
520 $a The anisotropic lattice thermal diffusivity of three olivines (Fo 0, Fo78, and Fo91), one orthopyroxene (En 91), and one clinopyroxene (Di72He9Jd3Cr 3Ts12) have been measured via impulsive stimulated light scattering, permitting the calculation of their lattice thermal diffusivity tensors to high temperatures. For Fo0 olivine, measurements extend from room temperature to 600°C, for Fo78 to 900°C, and for Fo91 to 1000°C, all in steps of 100°C. The orthopyroxene also was taken in steps to 1000°C, while the clinopyroxene was measured at room temperature. A limited set of room-temperature measurements to 5 GPa on a fourth olivine (Fo89) is also included. Diffusivities have been combined with calculations of density and specific heat to determine the lattice thermal conductivity tensors. An earlier theory that explains the observed behavior in terms of a positive lower bound on the phonon mean free path is discussed, and the data are used to constrain a model of thermal conductivity at high temperature. The relative contributions of optic and acoustic modes are evaluated from analysis of published dispersion curves. Five conclusions are reached: First, the anisotropy of lattice thermal conductivity remains essentially unchanged over the observed range of temperatures, indicating that anisotropy remains significant under upper-mantle conditions, and, in regions displaying preferred alignment, may account for observed lateral variations in the geotherm. Second, thermal conductivity departs significantly from earlier predictions of its temperature dependence; this may be understood in terms of a phonon mean free path that cannot diminish below 1.75 times the mean interatomic spacing. Third, for olivine, the optic modes have group velocities that are approximately one-third those of the acoustic modes, and do not dominate lattice conduction despite their greater number. Fourth, impurity scattering is significant along the olivine Fe-Mg solid solution series, but is not appreciable near the endpoints and therefore likely does not play a major role in the upper mantle. Fifth, the historic underestimation of lattice thermal conductivity at temperature has led to an overestimation of radiative conductivity; radiative transport, although significant, plays an even smaller role in the upper mantle than has heretofore been assumed.
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773 0 $t Dissertation Abstracts International $g 63-05B.
790 1 0 $a Brown, John Michael, $e advisor
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791 $a Ph.D.
792 $a 2002
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoeng/servlet/advanced?query=3053509