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The kinetics of chlorine atom reacti...

Quant, Claudia.

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The kinetics of chlorine atom reactions with naphthalene and alkylnaphthalenes.

Record Type:	Electronic resources : Monograph/item
Title/Author:	The kinetics of chlorine atom reactions with naphthalene and alkylnaphthalenes./
Author:	Quant, Claudia.
Description:	130 p.
Notes:	Source: Masters Abstracts International, Volume: 42-06, page: 2203.
Contained By:	Masters Abstracts International42-06.
Subject:	Chemistry, Analytical. -
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=1419641
ISBN:	0496243942

The kinetics of chlorine atom reactions with naphthalene and alkylnaphthalenes.
Quant, Claudia.

The kinetics of chlorine atom reactions with naphthalene and alkylnaphthalenes. - 130 p.

Source: Masters Abstracts International, Volume: 42-06, page: 2203.

Thesis (M.S.)--California State University, Fullerton, 2004.

Gas chromatography and the relative rate method have been used to study the kinetics and mechanisms of Cl atom reactions with naphthalene and alkylnaphthalenes at 298 K and 1 atm. An upper limit for the reaction rate constant for naphthalene has been determined to be 3 x 10-12 cm3molecule-1s-1. The reported rate constant is an upper limit value due to a possible interference by secondary radicals. Preliminary results suggest that the alkylnaphthalene rate constants are significantly faster, but measurements may also be subject to an interference. The kinetic isotope effect (KIE) and the product analysis indicate that the reaction of Cl atoms with naphthalene occurs predominantly via radical addition to the aromatic ring. A similar analysis of the Cl atom and 1-methylnapthalene reaction suggests that the reaction proceeds via both addition and abstraction. A comparison to reactions with OH and NO3 radicals, along with the implications to fundamental and atmospheric chemistry, are also discussed.

ISBN: 0496243942Subjects--Topical Terms:

586156
Chemistry, Analytical.

The kinetics of chlorine atom reactions with naphthalene and alkylnaphthalenes.
LDR:01860nmm 2200265 4500 001 1848772
005 20051202071437.5
008 130614s2004 eng d
020 $a 0496243942
035 $a (UnM)AAI1419641
035 $a AAI1419641
040 $a UnM $c UnM
100 1 $a Quant, Claudia. $3 1936770
245 1 4 $a The kinetics of chlorine atom reactions with naphthalene and alkylnaphthalenes.
300 $a 130 p.
500 $a Source: Masters Abstracts International, Volume: 42-06, page: 2203.
500 $a Chair: Scott Hewitt.
502 $a Thesis (M.S.)--California State University, Fullerton, 2004.
520 $a Gas chromatography and the relative rate method have been used to study the kinetics and mechanisms of Cl atom reactions with naphthalene and alkylnaphthalenes at 298 K and 1 atm. An upper limit for the reaction rate constant for naphthalene has been determined to be 3 x 10-12 cm3molecule-1s-1. The reported rate constant is an upper limit value due to a possible interference by secondary radicals. Preliminary results suggest that the alkylnaphthalene rate constants are significantly faster, but measurements may also be subject to an interference. The kinetic isotope effect (KIE) and the product analysis indicate that the reaction of Cl atoms with naphthalene occurs predominantly via radical addition to the aromatic ring. A similar analysis of the Cl atom and 1-methylnapthalene reaction suggests that the reaction proceeds via both addition and abstraction. A comparison to reactions with OH and NO3 radicals, along with the implications to fundamental and atmospheric chemistry, are also discussed.
590 $a School code: 6060.
650 4 $a Chemistry, Analytical. $3 586156
690 $a 0486
710 2 0 $a California State University, Fullerton. $3 1017845
773 0 $t Masters Abstracts International $g 42-06.
790 1 0 $a Hewitt, Scott, $e advisor
790 $a 6060
791 $a M.S.
792 $a 2004
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=1419641