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Synthesis and reactivity of palladiu...

Culkin, Darcy Ann.

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Synthesis and reactivity of palladium complexes of functionalized alkyls. Selection of catalysts for the alpha-arylation of nitriles and amides.

Record Type:	Electronic resources : Monograph/item
Title/Author:	Synthesis and reactivity of palladium complexes of functionalized alkyls. Selection of catalysts for the alpha-arylation of nitriles and amides./
Author:	Culkin, Darcy Ann.
Description:	285 p.
Notes:	Source: Dissertation Abstracts International, Volume: 65-03, Section: B, page: 1316.
Contained By:	Dissertation Abstracts International65-03B.
Subject:	Chemistry, Inorganic. -
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3125179
ISBN:	049672469X

Synthesis and reactivity of palladium complexes of functionalized alkyls. Selection of catalysts for the alpha-arylation of nitriles and amides.
Culkin, Darcy Ann.

Synthesis and reactivity of palladium complexes of functionalized alkyls. Selection of catalysts for the alpha-arylation of nitriles and amides. - 285 p.

Source: Dissertation Abstracts International, Volume: 65-03, Section: B, page: 1316.

Thesis (Ph.D.)--Yale University, 2004.

A series of arylpalladium alkyl complexes containing varied functional groups alpha to the metal was prepared to reveal the effect of ligand steric and electronic properties on structure, stability, and reactivity. Arylpalladium complexes of methyl, benzyl, enolate, cyanoalkyl, and trifluoroethyl groups underwent carbon-carbon bond-forming reductive elimination upon heating. Mechanistic studies of the reductive elimination process led to the discovery of a new coupling reaction, the palladium-catalyzed alpha-arylation of nitriles, and to the development of improved methods for the palladium-catalyzed synthesis of alpha-aryl amides.

ISBN: 049672469XSubjects--Topical Terms:

517253
Chemistry, Inorganic.

Synthesis and reactivity of palladium complexes of functionalized alkyls. Selection of catalysts for the alpha-arylation of nitriles and amides.
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100 1 $a Culkin, Darcy Ann. $3 1932485
245 1 0 $a Synthesis and reactivity of palladium complexes of functionalized alkyls. Selection of catalysts for the alpha-arylation of nitriles and amides.
300 $a 285 p.
500 $a Source: Dissertation Abstracts International, Volume: 65-03, Section: B, page: 1316.
500 $a Director: John F. Hartwig.
502 $a Thesis (Ph.D.)--Yale University, 2004.
520 $a A series of arylpalladium alkyl complexes containing varied functional groups alpha to the metal was prepared to reveal the effect of ligand steric and electronic properties on structure, stability, and reactivity. Arylpalladium complexes of methyl, benzyl, enolate, cyanoalkyl, and trifluoroethyl groups underwent carbon-carbon bond-forming reductive elimination upon heating. Mechanistic studies of the reductive elimination process led to the discovery of a new coupling reaction, the palladium-catalyzed alpha-arylation of nitriles, and to the development of improved methods for the palladium-catalyzed synthesis of alpha-aryl amides.
590 $a School code: 0265.
650 4 $a Chemistry, Inorganic. $3 517253
650 4 $a Chemistry, Organic. $3 516206
690 $a 0488
690 $a 0490
710 2 0 $a Yale University. $3 515640
773 0 $t Dissertation Abstracts International $g 65-03B.
790 1 0 $a Hartwig, John F., $e advisor
790 $a 0265
791 $a Ph.D.
792 $a 2004
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3125179