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Wastewater treatment by catalytic we...
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Wu, Qiang.
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Wastewater treatment by catalytic wet air oxidation in a continuous pilot-scale trickle bed reactor.
紀錄類型:
書目-電子資源 : Monograph/item
正題名/作者:
Wastewater treatment by catalytic wet air oxidation in a continuous pilot-scale trickle bed reactor./
作者:
Wu, Qiang.
面頁冊數:
183 p.
附註:
Source: Dissertation Abstracts International, Volume: 65-02, Section: B, page: 0637.
Contained By:
Dissertation Abstracts International65-02B.
標題:
Environmental Sciences. -
電子資源:
http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3123043
ISBN:
0496703565
Wastewater treatment by catalytic wet air oxidation in a continuous pilot-scale trickle bed reactor.
Wu, Qiang.
Wastewater treatment by catalytic wet air oxidation in a continuous pilot-scale trickle bed reactor.
- 183 p.
Source: Dissertation Abstracts International, Volume: 65-02, Section: B, page: 0637.
Thesis (Ph.D.)--Hong Kong University of Science and Technology (People's Republic of China), 2004.
This work is an in-depth study on the application of a catalytic wet air oxidation (CWAO) process for continuous wastewater treatment.
ISBN: 0496703565Subjects--Topical Terms:
676987
Environmental Sciences.
Wastewater treatment by catalytic wet air oxidation in a continuous pilot-scale trickle bed reactor.
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Source: Dissertation Abstracts International, Volume: 65-02, Section: B, page: 0637.
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Adviser: P. L. Yue; Xijun Hu.
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To this end, first various catalysts were prepared and their feasibility for phenol degradation was evaluated in a batch slurry reactor. Activated carbon-based copper (Cu/AC) was found to be the best catalyst, A fully instrumented pilot scale trickle bed reactor (TBR) was then used as a reactor in which oxygen and aqueous phenol were fed co-currently over the Cu/AC catalyst.
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This TBR proved to be able to detoxify effectively wastewater containing phenol. A systematic study was conducted to investigate the mass transfer and reaction processes in the TBR. Both gas-to-liquid and liquid-to-solid mass transfer-related parameters were measured and correlated. The reaction kinetics for phenol degradation by both copper salts (homogeneous catalyst) and Cu/AC (heterogeneous catalyst) were examined. Kinetics models for representing the rate data were established and validated.
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On the basis of the above results, a comprehensive mathematical model for the TBR was developed. The model was found to be capable of predicting the phenol conversion rate over a range of operational conditions.
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