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Fructose autoxidation produces hydro...

Jang, Hangjun.

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Fructose autoxidation produces hydroxyl radical and glyoxal that damage biomolecules.

Record Type:	Electronic resources : Monograph/item
Title/Author:	Fructose autoxidation produces hydroxyl radical and glyoxal that damage biomolecules./
Author:	Jang, Hangjun.
Description:	45 p.
Notes:	Source: Masters Abstracts International, Volume: 45-01, page: 0316.
Contained By:	Masters Abstracts International45-01.
Subject:	Chemistry, Analytical. -
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=1438420
ISBN:	9780542903496

Fructose autoxidation produces hydroxyl radical and glyoxal that damage biomolecules.
Jang, Hangjun.

Fructose autoxidation produces hydroxyl radical and glyoxal that damage biomolecules. - 45 p.

Source: Masters Abstracts International, Volume: 45-01, page: 0316.

Thesis (M.S.)--Long Island University, The Brooklyn Center, 2006.

Background. Fructose is one of the most commonly used sweeteners in food industry and large consumption of it has been blamed for marked increase in obese population. Also, high fructose diet has not only induced insulin resistance syndrome that comprises obesity, hypertension, and glucose intolerance but also caused oxidative damage to protein in rodents. Hypothesis. Based upon its chemical structure, fructose may have higher oxidative potential than glucose, resulting in formation of more free radical and dicarbonyl than glucose. Goals. Fructose has been studied regarding its free radical and dicarbonyl formation in comparison to common dietary mono saccharides, glucose, galactose, ribose and the most reactive triose, glyceraldehyde. Method. Five sugars, glucose, galactose, fructose, ribose, and glyceraldehyde were separately incubated in pH 7.4 phosphate buffer at 37°C in the presence or absence of L-lysine for 18 days. All the reaction vessels contain 10 muM FeSO4 as a catalyst for autoxidation of monosaccharide. A portion of reaction mixture was collected every third day for HPLC assay of hydroxyl radical reaction with salicylic acid and dicarbonyl reaction with Girard-T reagent. Result. In the absence of amino acid, glyceraldehyde generated the highest amounts of hydroxyl radical. Next was fructose and ribose that showed marginal difference in hydroxyl radical generation. (Abstract shortened by UMI.)

ISBN: 9780542903496Subjects--Topical Terms:

586156
Chemistry, Analytical.

Fructose autoxidation produces hydroxyl radical and glyoxal that damage biomolecules.
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035 $a (UnM)AAI1438420
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100 1 $a Jang, Hangjun. $3 1920737
245 1 0 $a Fructose autoxidation produces hydroxyl radical and glyoxal that damage biomolecules.
300 $a 45 p.
500 $a Source: Masters Abstracts International, Volume: 45-01, page: 0316.
500 $a Adviser: Gregory Edens.
502 $a Thesis (M.S.)--Long Island University, The Brooklyn Center, 2006.
520 $a Background. Fructose is one of the most commonly used sweeteners in food industry and large consumption of it has been blamed for marked increase in obese population. Also, high fructose diet has not only induced insulin resistance syndrome that comprises obesity, hypertension, and glucose intolerance but also caused oxidative damage to protein in rodents. Hypothesis. Based upon its chemical structure, fructose may have higher oxidative potential than glucose, resulting in formation of more free radical and dicarbonyl than glucose. Goals. Fructose has been studied regarding its free radical and dicarbonyl formation in comparison to common dietary mono saccharides, glucose, galactose, ribose and the most reactive triose, glyceraldehyde. Method. Five sugars, glucose, galactose, fructose, ribose, and glyceraldehyde were separately incubated in pH 7.4 phosphate buffer at 37°C in the presence or absence of L-lysine for 18 days. All the reaction vessels contain 10 muM FeSO4 as a catalyst for autoxidation of monosaccharide. A portion of reaction mixture was collected every third day for HPLC assay of hydroxyl radical reaction with salicylic acid and dicarbonyl reaction with Girard-T reagent. Result. In the absence of amino acid, glyceraldehyde generated the highest amounts of hydroxyl radical. Next was fructose and ribose that showed marginal difference in hydroxyl radical generation. (Abstract shortened by UMI.)
590 $a School code: 0198.
650 4 $a Chemistry, Analytical. $3 586156
650 4 $a Chemistry, Biochemistry. $3 1017722
690 $a 0486
690 $a 0487
710 2 0 $a Long Island University, The Brooklyn Center. $3 1017735
773 0 $t Masters Abstracts International $g 45-01.
790 1 0 $a Edens, Gregory, $e advisor
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791 $a M.S.
792 $a 2006
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=1438420