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Experimental Constraints on Lithium ...

Caciagli Warman, Natalie.

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Experimental Constraints on Lithium Exchange between Clinopyroxene, Olivine and Aqueous Fluid at High Pressures and Temperatures.

Record Type:	Language materials, printed : Monograph/item
Title/Author:	Experimental Constraints on Lithium Exchange between Clinopyroxene, Olivine and Aqueous Fluid at High Pressures and Temperatures./
Author:	Caciagli Warman, Natalie.
Description:	163 p.
Notes:	Source: Dissertation Abstracts International, Volume: 72-07, Section: B, page: .
Contained By:	Dissertation Abstracts International72-07B.
Subject:	Geochemistry. -
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=NR73078
ISBN:	9780494730782

Experimental Constraints on Lithium Exchange between Clinopyroxene, Olivine and Aqueous Fluid at High Pressures and Temperatures.
Caciagli Warman, Natalie.

Experimental Constraints on Lithium Exchange between Clinopyroxene, Olivine and Aqueous Fluid at High Pressures and Temperatures. - 163 p.

Source: Dissertation Abstracts International, Volume: 72-07, Section: B, page: .

Thesis (Ph.D.)--University of Toronto (Canada), 2010.

Clinopyroxene, olivine, plagioclase and hydrous fluid lithium partition coefficients have been measured between 800-1100°C at 1 GPa. Clinopyroxene-fluid partitioning is a function of temperature (ln DLi cpx/fluid = -7.3 (+/-0.5) + 7.0 ( +/-0.7) * 1000/T) and appears to increase with increasing pyroxene Al2O3 content. Olivine-fluid partitioning of lithium is a function of temperature (ln DLiol/fluid = -6.0 (+/-2.0) + 6.5 (+/-2.0) * 1000/T) and appears to be sensitive to olivine Mg/Fe content. Anorthite-fluid lithium partitioning is a function of feldspar composition, similar to the partitioning of other cations in the feldspar-fluid system. Isotopic fractionation between clinopyroxene and fluid, DeltaLicpx-fluid , has been measured between 900-1100°C and ranges from - 0.3 to -3.4 &permil; (+/-1.4 &permil;).

ISBN: 9780494730782Subjects--Topical Terms:

539092
Geochemistry.

Experimental Constraints on Lithium Exchange between Clinopyroxene, Olivine and Aqueous Fluid at High Pressures and Temperatures.
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020 $a 9780494730782
035 $a (UMI)AAINR73078
035 $a AAINR73078
040 $a UMI $c UMI
100 1 $a Caciagli Warman, Natalie. $3 1679283
245 1 0 $a Experimental Constraints on Lithium Exchange between Clinopyroxene, Olivine and Aqueous Fluid at High Pressures and Temperatures.
300 $a 163 p.
500 $a Source: Dissertation Abstracts International, Volume: 72-07, Section: B, page: .
502 $a Thesis (Ph.D.)--University of Toronto (Canada), 2010.
520 $a Clinopyroxene, olivine, plagioclase and hydrous fluid lithium partition coefficients have been measured between 800-1100°C at 1 GPa. Clinopyroxene-fluid partitioning is a function of temperature (ln DLi cpx/fluid = -7.3 (+/-0.5) + 7.0 ( +/-0.7) * 1000/T) and appears to increase with increasing pyroxene Al2O3 content. Olivine-fluid partitioning of lithium is a function of temperature (ln DLiol/fluid = -6.0 (+/-2.0) + 6.5 (+/-2.0) * 1000/T) and appears to be sensitive to olivine Mg/Fe content. Anorthite-fluid lithium partitioning is a function of feldspar composition, similar to the partitioning of other cations in the feldspar-fluid system. Isotopic fractionation between clinopyroxene and fluid, DeltaLicpx-fluid , has been measured between 900-1100°C and ranges from - 0.3 to -3.4 &permil; (+/-1.4 &permil;).
520 $a Lithium diffusion has been measured in clinopyroxene at 800-1000°C and in olivine at 1000°C. The lithium diffusion coefficient is independent of the diffusion gradient as values are the same if the flux of lithium is into or out of the crystal and ranges from -15.19 +/- 2.86 m2 /s at 800°C to - 11.97 +/- 0.86 m2/s at 1000°C. Lithium diffusion in olivine was found to be two orders of magnitude slower than for clinopyroxene at similar conditions. Closure temperatures calculated for lithium diffusion in clinopyroxene range from &sim;400 to &sim;600°C. These results demonstrate that lithium equilibration between fluids and minerals is instantaneous, on a geological timescales.
520 $a The confirmation of instantaneous equilibration, combined with min-fluid partition coefficients and values for DeltaLicpx-fluid, permits quantitative modeling of the evolution of lithium concentration and isotopic composition in slab-derived fluids during transport to the arc melt source. Our results indicate that fluids migrating by porous flow will rapidly exchange lithium with the mantle, effectively buffering the fluid composition close to ambient mantle values, and rapidly attenuating the slab lithium signature. Fluid transport mechanisms involving fracture flow are required to maintain a slab-like lithium signature (both elemental and isotopic) from the slab to the melt source of island arc basalts.
520 $a This study demonstrates that mineral-fluid equilibration is rapid, and as a result the lithium content of minerals can only reliably represent chemical exchange in the very latest stages of the sample's history.
590 $a School code: 0779.
650 4 $a Geochemistry. $3 539092
690 $a 0996
710 2 $a University of Toronto (Canada). $3 1017674
773 0 $t Dissertation Abstracts International $g 72-07B.
790 $a 0779
791 $a Ph.D.
792 $a 2010
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=NR73078