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Xenon polarizer characterization and...

Schrank, Geoffry M.

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Xenon polarizer characterization and biological studies.

Record Type:	Language materials, printed : Monograph/item
Title/Author:	Xenon polarizer characterization and biological studies./
Author:	Schrank, Geoffry M.
Description:	128 p.
Notes:	Source: Dissertation Abstracts International, Volume: 71-05, Section: B, page: 3102.
Contained By:	Dissertation Abstracts International71-05B.
Subject:	Physics, Atomic. -
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3406167
ISBN:	9781109728538

Xenon polarizer characterization and biological studies.
Schrank, Geoffry M.

Xenon polarizer characterization and biological studies. - 128 p.

Source: Dissertation Abstracts International, Volume: 71-05, Section: B, page: 3102.

Thesis (Ph.D.)--The University of Utah, 2010.

I will describe a low-pressure flow-through 129Xe polarizer and report its performance by examining both the output 129Xe and in situ Rb polarization. The 129Xe polarization was made using standard NMR techniques, and the Rb polarization measurement was made using optically detected electron paramagnetic resonance. I compared the results of these measurements to a one-dimensional numerical model of the system. While we qualitatively understand the behavior of the system, the comparison between measurement and model reveals several inadequacies in our understanding of many important physical mechanisms. I will discuss the relevant physics necessary to qualitatively understand the system's behavior and suggest what mechanisms may cause the discrepancies in the modeled and measured behavior.

ISBN: 9781109728538Subjects--Topical Terms:

1029235
Physics, Atomic.

Xenon polarizer characterization and biological studies.
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020 $a 9781109728538
035 $a (UMI)AAI3406167
035 $a AAI3406167
040 $a UMI $c UMI
100 1 $a Schrank, Geoffry M. $3 1678209
245 1 0 $a Xenon polarizer characterization and biological studies.
300 $a 128 p.
500 $a Source: Dissertation Abstracts International, Volume: 71-05, Section: B, page: 3102.
502 $a Thesis (Ph.D.)--The University of Utah, 2010.
520 $a I will describe a low-pressure flow-through 129Xe polarizer and report its performance by examining both the output 129Xe and in situ Rb polarization. The 129Xe polarization was made using standard NMR techniques, and the Rb polarization measurement was made using optically detected electron paramagnetic resonance. I compared the results of these measurements to a one-dimensional numerical model of the system. While we qualitatively understand the behavior of the system, the comparison between measurement and model reveals several inadequacies in our understanding of many important physical mechanisms. I will discuss the relevant physics necessary to qualitatively understand the system's behavior and suggest what mechanisms may cause the discrepancies in the modeled and measured behavior.
520 $a I will demonstrate the utility of this Xe polarizer by measuring xenon's chemical shift dependence on the concentration of Bovine Pancreatic Trypsin Inhibitor (BPTI) and some of its mutants. Mutants Y23A and F45G have measured dependence of 0.56+/-0.05 ppm/mM and 0.47+/-0.07 ppm/mM, respectively, which is consistent with relatively strong, manufactured binding sites in the structure. Wild type BPTI has a measured dependence of only 0.15+/-0.02 ppm/mM, suggesting that there exists no specific binding site to which Xe can bind. Finally, the mutant Y35G has a dependence of 0.10+/-0.07 ppm/mM. This, with previous data, suggests that a large fraction of solution-phase Y35G does not exist in a conformation that allows Xe access to its binding cavity.
590 $a School code: 0240.
650 4 $a Physics, Atomic. $3 1029235
650 4 $a Physics, Optics. $3 1018756
690 $a 0748
690 $a 0752
710 2 $a The University of Utah. $3 1017410
773 0 $t Dissertation Abstracts International $g 71-05B.
790 $a 0240
791 $a Ph.D.
792 $a 2010
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3406167