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Anisotropic nanomaterials: Synthesis...
~
Banholzer, Matthew John.
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Anisotropic nanomaterials: Synthesis, optical and magnetic properties, and applications.
Record Type:
Language materials, printed : Monograph/item
Title/Author:
Anisotropic nanomaterials: Synthesis, optical and magnetic properties, and applications./
Author:
Banholzer, Matthew John.
Description:
137 p.
Notes:
Source: Dissertation Abstracts International, Volume: 71-10, Section: B, page: 6137.
Contained By:
Dissertation Abstracts International71-10B.
Subject:
Chemistry, Inorganic. -
Online resource:
http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3419016
ISBN:
9781124183831
Anisotropic nanomaterials: Synthesis, optical and magnetic properties, and applications.
Banholzer, Matthew John.
Anisotropic nanomaterials: Synthesis, optical and magnetic properties, and applications.
- 137 p.
Source: Dissertation Abstracts International, Volume: 71-10, Section: B, page: 6137.
Thesis (Ph.D.)--Northwestern University, 2010.
As nanoscience and nanotechnology mature, anisotropic metal nanostructures are emerging in a variety of contexts as valuable class of nanostructures due to their distinctive attributes. With unique properties ranging from optical to magnetic and beyond, these structures are useful in many new applications.
ISBN: 9781124183831Subjects--Topical Terms:
517253
Chemistry, Inorganic.
Anisotropic nanomaterials: Synthesis, optical and magnetic properties, and applications.
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Anisotropic nanomaterials: Synthesis, optical and magnetic properties, and applications.
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137 p.
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Source: Dissertation Abstracts International, Volume: 71-10, Section: B, page: 6137.
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Adviser: Chad A. Mirkin.
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Thesis (Ph.D.)--Northwestern University, 2010.
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As nanoscience and nanotechnology mature, anisotropic metal nanostructures are emerging in a variety of contexts as valuable class of nanostructures due to their distinctive attributes. With unique properties ranging from optical to magnetic and beyond, these structures are useful in many new applications.
520
$a
Chapter two discusses the nanodisk code: a linear array of metal disk pairs that serve as surface-enhanced Raman scattering substrates. These multiplexing structures employ a binary encoding scheme, perform better than previous nanowires designs (in the context of SERS) and are useful for both convert encoding and tagging of substrates (based both on spatial disk position and spectroscopic response) as well as biomolecule detection (e.g. DNA).
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Chapter three describes the development of improved, silver-based nanodisk code structures. Work was undertaken to generate structures with high yield and reproducibility and to reoptimize the geometry of each disk pair for maximum Raman enhancement. The improved silver structures exhibit greater enhancement than Au structures (leading to lower DNA detection limits), convey additional flexibility, and enable trinary encoding schemes where far more unique structures can be created.
520
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Chapter four considers the effect of roughness on the plasmonic properties of nanorod structures and introduces a novel method to smooth the end-surfaces of nanorods structures. The smoothing technique is based upon a two-step process relying upon diffusion control during nanowires growth and selective oxidation after each step of synthesis is complete. Empirical and theoretical work show that smoothed nanostructures have superior and controllable optical properties.
520
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Chapter five concerns silica-encapsulated gold nanoprisms. This encapsulation allows these highly sensitive prisms to remain stable and protected in solution, enabling their use as class-leading sensors. Theoretical study complements the empirical work, exploring the effect of encapsulation on the SPR of these structures.
520
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Chapter six focuses on the magnetic properties of Au-Ni heterostructures. In addition to demonstration of nanoconfinement effects based upon the anisotropy of the nanorods/nanodisk structure, the magnetic coupling of rod-disk heterostructures is examined. Subsequent investigations suggest that the magnetic behavior of disks can be influenced by nearby rod segments, leading to the creation of a three-state spin system that may prove useful in device applications.
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School code: 0163.
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http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3419016
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