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Semifluorinated polymers via cycload...

Iacono, Scott Thomas.

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Semifluorinated polymers via cycloaddition and nucleophilic addition reactions of aromatic trifluorovinyl ethers.

Record Type:	Language materials, printed : Monograph/item
Title/Author:	Semifluorinated polymers via cycloaddition and nucleophilic addition reactions of aromatic trifluorovinyl ethers./
Author:	Iacono, Scott Thomas.
Description:	480 p.
Notes:	Adviser: Dennis W. Smith, Jr.
Contained By:	Dissertation Abstracts International69-03B.
Subject:	Chemistry, Organic. -
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3304076
ISBN:	9780549520757

Semifluorinated polymers via cycloaddition and nucleophilic addition reactions of aromatic trifluorovinyl ethers.
Iacono, Scott Thomas.

Semifluorinated polymers via cycloaddition and nucleophilic addition reactions of aromatic trifluorovinyl ethers. - 480 p.

Adviser: Dennis W. Smith, Jr.

Thesis (Ph.D.)--Clemson University, 2008.

This dissertation encompasses the synthesis, characterization, and properties of semifluorinated polymers derived from thermal polymerization of aryl trifluorovinyl ether (TFVE) monomers. This work is divided into two parts based on the methodology of thermal polymerization using aryl TFVE monomers.

ISBN: 9780549520757Subjects--Topical Terms:

516206
Chemistry, Organic.

Semifluorinated polymers via cycloaddition and nucleophilic addition reactions of aromatic trifluorovinyl ethers.
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020 $a 9780549520757
035 $a (UMI)AAI3304076
035 $a AAI3304076
040 $a UMI $c UMI
100 1 $a Iacono, Scott Thomas. $3 1286034
245 1 0 $a Semifluorinated polymers via cycloaddition and nucleophilic addition reactions of aromatic trifluorovinyl ethers.
300 $a 480 p.
500 $a Adviser: Dennis W. Smith, Jr.
500 $a Source: Dissertation Abstracts International, Volume: 69-03, Section: B, page: 1676.
502 $a Thesis (Ph.D.)--Clemson University, 2008.
520 $a This dissertation encompasses the synthesis, characterization, and properties of semifluorinated polymers derived from thermal polymerization of aryl trifluorovinyl ether (TFVE) monomers. This work is divided into two parts based on the methodology of thermal polymerization using aryl TFVE monomers.
520 $a The first part of this work involves the thermal [2 + 2] cyclodimerization of aryl TFVE monomers affording perfluorocyclobutyl (PFCB) aryl ether polymers. Chapter 1 provides an overview of PFCB aryl ether polymers as a next-generation class of high performance fluoropolymers that have been successfully employed for a myriad of technologies. PFCB aryl ether polymers are highly desired because of their high thermal stability, processability, and tailorability for specific material applications. Chapter 2 introduces a general perspective of polyhedral oligomeric silsesquioxanes (POSS) that were modified with PFCB aryl ether polymer for property enhancement, specifically for low surface energy materials. Chapter 3 and 4 show the synthesis, characterization, and properties of POSS modified PFCB aryl ether polymers as blends and a variety of copolymer architectures, respectively.
520 $a The second portion of this dissertation focuses on the development of a new, facile step-growth polymerization of diols/bisphenols and aryl TFVEs to afford fluoroethylene/vinylene alkyl/aryl ether (FAE) polymers. Chapter 5 is a prelude to the development of FAE polymers which entails optimizing the methodology and mechanistic rationale of nucleophile addition to aryl TFVEs. Chapter 6 details the FAE polymerization kinetics, physical properties, and strategy for functionalization. Chapter 7 illustrates the modular modification of FAE polymers for the development of tunable light emissive materials for potential use as transport layer material for organic light emitting diodes (OLEDs) and also chemical sensors. Chapter 8 introduces postfunctionaliztion of FAE polymers resulting with sulfonated biaryl segments for the development of proton exchange membranes (PEMs) for fuel cells. Chapter 9 involves the development of bis-ortho-diynylarene (BODA) monomers for the development of high yielding and moldable glassy-carbon microstructures. The adhesion, wettability, density, and coefficient of thermal expansion of BODA-derived glassy carbon are discussed.
590 $a School code: 0050.
650 4 $a Chemistry, Organic. $3 516206
650 4 $a Chemistry, Polymer. $3 1018428
650 4 $a Engineering, Materials Science. $3 1017759
690 $a 0490
690 $a 0495
690 $a 0794
710 2 $a Clemson University. $b Chemistry. $3 1030764
773 0 $t Dissertation Abstracts International $g 69-03B.
790 $a 0050
790 1 0 $a DesMarteau, Darryl D. $e committee member
790 1 0 $a Dieter, Karl $e committee member
790 1 0 $a Mabry, Joseph M. $e committee member
790 1 0 $a Pennington, William T. $e committee member
790 1 0 $a Smith, Dennis W., Jr., $e advisor
791 $a Ph.D.
792 $a 2008
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3304076