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The anomalous oxygen isotopic compos...

Hoag, Katherine Jean.

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The anomalous oxygen isotopic composition of atmospheric carbon dioxide and applications to the carbon cycle and stratospheric chemisty and transport.

紀錄類型:	書目-語言資料,印刷品 : Monograph/item
正題名/作者:	The anomalous oxygen isotopic composition of atmospheric carbon dioxide and applications to the carbon cycle and stratospheric chemisty and transport./
作者:	Hoag, Katherine Jean.
面頁冊數:	114 p.
附註:	Adviser: Kristie A. Boering.
Contained By:	Dissertation Abstracts International69-03B.
Subject:	Atmospheric Sciences. -
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3306166
ISBN:	9780549528685

The anomalous oxygen isotopic composition of atmospheric carbon dioxide and applications to the carbon cycle and stratospheric chemisty and transport.
Hoag, Katherine Jean.

The anomalous oxygen isotopic composition of atmospheric carbon dioxide and applications to the carbon cycle and stratospheric chemisty and transport. - 114 p.

Adviser: Kristie A. Boering.

Thesis (Ph.D.)--University of California, Berkeley, 2007.

This dissertation reports new measurements of stratospheric 17 O-CO2 and 18O-CO2, doubling the existing dataset and providing new knowledge regarding the variation in 17O-CO2 and 18O-CO2 throughout the stratosphere. The measurements reveal an unexpectedly large slope of 2.3 for the 17O/16O:18O/16 O relationship, compared with values of 1.2 to 1.7 from previous measurements and values of 1.0 to 1.7 in models, differences that are robust with respect to regression statistics and analytical precisions of 0.2&permil; for &dgr; 17O and 0.1&permil; for &dgr;18O. Hypotheses explaining these discrepancies include 2-endmember mixing between less isotopically-enriched, lower stratospheric air with more enriched, upper stratospheric or mesospheric air, differences in the mesosphere-stratosphere mixing predicted by models, and/or latitudinal variations in the anomalous or mass-dependent isotope effects controlling the 17O anomaly in CO2. As such, the new measurements provide important new constraints on the underlying isotope effects and how they are modified by atmospheric transport. These results also indicate that the optimal locations for future measurements are the upper and the tropical stratosphere.

ISBN: 9780549528685Subjects--Topical Terms:

1019179
Atmospheric Sciences.

The anomalous oxygen isotopic composition of atmospheric carbon dioxide and applications to the carbon cycle and stratospheric chemisty and transport.
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245 1 4 $a The anomalous oxygen isotopic composition of atmospheric carbon dioxide and applications to the carbon cycle and stratospheric chemisty and transport.
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500 $a Adviser: Kristie A. Boering.
500 $a Source: Dissertation Abstracts International, Volume: 69-03, Section: B, page: 1517.
502 $a Thesis (Ph.D.)--University of California, Berkeley, 2007.
520 $a This dissertation reports new measurements of stratospheric 17 O-CO2 and 18O-CO2, doubling the existing dataset and providing new knowledge regarding the variation in 17O-CO2 and 18O-CO2 throughout the stratosphere. The measurements reveal an unexpectedly large slope of 2.3 for the 17O/16O:18O/16 O relationship, compared with values of 1.2 to 1.7 from previous measurements and values of 1.0 to 1.7 in models, differences that are robust with respect to regression statistics and analytical precisions of 0.2&permil; for &dgr; 17O and 0.1&permil; for &dgr;18O. Hypotheses explaining these discrepancies include 2-endmember mixing between less isotopically-enriched, lower stratospheric air with more enriched, upper stratospheric or mesospheric air, differences in the mesosphere-stratosphere mixing predicted by models, and/or latitudinal variations in the anomalous or mass-dependent isotope effects controlling the 17O anomaly in CO2. As such, the new measurements provide important new constraints on the underlying isotope effects and how they are modified by atmospheric transport. These results also indicate that the optimal locations for future measurements are the upper and the tropical stratosphere.
520 $a Modeling performed for this dissertation shows that the anomalous 17O enrichments in stratospheric CO2 can also provide a new constraint on gross carbon fluxes between the atmosphere and biosphere. A box model was used to investigate the balance between stratospheric production of the 17O anomaly and destruction and dilution by the biosphere. Tropospheric Delta17O-CO2 is predicted to be 0.1&permil; and sensitive to changes in variations in gross primary productivity. Therefore, measurements of Delta17O-CO2 will provide an important additional constraint on gross carbon fluxes, similar to &dgr;18O-CO 2 but dependent on fewer complex hydrological variables, such as &dgr; 18O-H2O.
520 $a This dissertation also reports net stratosphere-troposphere fluxes for &dgr; 18O-CO2, &dgr;13C-CH4, &dgr;D-CH 4, and &dgr;D-H2, determined empirically from stratospheric observations. The magnitudes of these fluxes indicate that the transport of isotopically-enriched gases from the stratosphere likely influences the meridional distribution or seasonality of the isotopic compositions measured at the surface. These isotope fluxes can now be included empirically for the first time in 3D models used to determine the latitude distribution of the various sources and sinks.
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