東華大學圖書館 |

語系: 繁體中文

說明(常見問題)

回圖書館首頁

手機版館藏查詢

登入

回首頁 到查詢結果 [ null ]

切換: 標籤 | MARC模式 | ISBD

Highly Dipole-Parallel Aligned Nonli...

Bhoday, Harmeet Singh,

FindBook

Google Book

Amazon

博客來

Highly Dipole-Parallel Aligned Nonlinear Optical Organic Molecular Crystalline Materials: Rational Design, Experimental and Theoretical Studies of Supramolecular Structures and Non-Covalent Interactions /

紀錄類型:	書目-電子資源 : Monograph/item
正題名/作者:	Highly Dipole-Parallel Aligned Nonlinear Optical Organic Molecular Crystalline Materials: Rational Design, Experimental and Theoretical Studies of Supramolecular Structures and Non-Covalent Interactions // Harmeet Singh Bhoday.
作者:	Bhoday, Harmeet Singh,
面頁冊數:	1 electronic resource (323 pages)
附註:	Source: Dissertations Abstracts International, Volume: 86-03, Section: B.
Contained By:	Dissertations Abstracts International86-03B.
標題:	Chemistry. -
電子資源:	https://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=31487235
ISBN:	9798384085546

Highly Dipole-Parallel Aligned Nonlinear Optical Organic Molecular Crystalline Materials: Rational Design, Experimental and Theoretical Studies of Supramolecular Structures and Non-Covalent Interactions /
Bhoday, Harmeet Singh,

Highly Dipole-Parallel Aligned Nonlinear Optical Organic Molecular Crystalline Materials: Rational Design, Experimental and Theoretical Studies of Supramolecular Structures and Non-Covalent Interactions /Harmeet Singh Bhoday. - 1 electronic resource (323 pages)

Source: Dissertations Abstracts International, Volume: 86-03, Section: B.

Highly dipole-parallel aligned donor-acceptor substituted organic molecules are attractive for a wide array of applications, including nonlinear optics. However, only a limited number of crystals are known to adopt polar non-centroymmetric space groups. The concepts guiding the fabrication of these polar materials have been described. The study focused on unsymmetrical donor-acceptor substituted azines and butadienes. An improved design over (MeO, Y)-azines led to the realization of three crystals perfectly aligned in dipole parallel orientation for (PhO, Y)-azines with Y = Cl, Br, I, and one nearly perfectly aligned crystal for Y = F (Paper I). The unique bonding properties associated with fluorine enabled the realization of both polar and non-polar PBAM stacking in (PhO, F)-azine (Paper II). The symmetrical azines were also studied extensively to understand the intermolecular interactions in azine crystals. Symmetry reduction of symmetrical (X, X)-azine molecules in idioteloamphiphile monolayers (IAMs) was observed, and an explanation based on interaction inventory analyses is discussed (Paper III). Additionally, the synthesis of four representatives of the new "methoxyphenyl series" of acetophenone azines, (MeO-Ph, Y)-azines is successfully described. The methoxyphenyl chromophore offers significantly improved nonlinear optical (NLO) performance compared to the methoxy and phenoxy series (Paper IV).Furthermore, a series of 1-(4'-halophenyl)-4-(4"-methoxyphenyl)buta-1,3-dienes with halogens was synthesized. (MeO, Y)-butadienes exhibit much higher first-order molecular hyperpolarizabilities than their analogous (MeO, Y)-azines due to their higher dipole moments and larger conjugation lengths (Paper V).

English

ISBN: 9798384085546Subjects--Topical Terms:

516420
Chemistry.
Subjects--Index Terms:

Dipole moments

Highly Dipole-Parallel Aligned Nonlinear Optical Organic Molecular Crystalline Materials: Rational Design, Experimental and Theoretical Studies of Supramolecular Structures and Non-Covalent Interactions /
LDR:03311nmm a22004093i 4500 001 2433740
005 20250905091002.5
006 m o d
007 cr|nu||||||||
008 261011s2024 miu||||||m |||||||eng d
020 $a 9798384085546
035 $a (MiAaPQD)AAI31487235
035 $a AAI31487235
040 $a MiAaPQD $b eng $c MiAaPQD $e rda
100 1 $a Bhoday, Harmeet Singh, $e author. $3 3823478
245 1 0 $a Highly Dipole-Parallel Aligned Nonlinear Optical Organic Molecular Crystalline Materials: Rational Design, Experimental and Theoretical Studies of Supramolecular Structures and Non-Covalent Interactions / $c Harmeet Singh Bhoday.
264 1 $a Ann Arbor : $b ProQuest Dissertations & Theses, $c 2024
300 $a 1 electronic resource (323 pages)
336 $a text $b txt $2 rdacontent
337 $a computer $b c $2 rdamedia
338 $a online resource $b cr $2 rdacarrier
500 $a Source: Dissertations Abstracts International, Volume: 86-03, Section: B.
500 $a Advisors: Glaser, Rainer Committee members: Winiarz, Jeffrey; Stavropoulos, Pericles; Grubbs, Garry Smitty; Yamilov, Alexey.
502 $b Ph.D. $c Missouri University of Science and Technology $d 2024.
520 $a Highly dipole-parallel aligned donor-acceptor substituted organic molecules are attractive for a wide array of applications, including nonlinear optics. However, only a limited number of crystals are known to adopt polar non-centroymmetric space groups. The concepts guiding the fabrication of these polar materials have been described. The study focused on unsymmetrical donor-acceptor substituted azines and butadienes. An improved design over (MeO, Y)-azines led to the realization of three crystals perfectly aligned in dipole parallel orientation for (PhO, Y)-azines with Y = Cl, Br, I, and one nearly perfectly aligned crystal for Y = F (Paper I). The unique bonding properties associated with fluorine enabled the realization of both polar and non-polar PBAM stacking in (PhO, F)-azine (Paper II). The symmetrical azines were also studied extensively to understand the intermolecular interactions in azine crystals. Symmetry reduction of symmetrical (X, X)-azine molecules in idioteloamphiphile monolayers (IAMs) was observed, and an explanation based on interaction inventory analyses is discussed (Paper III). Additionally, the synthesis of four representatives of the new "methoxyphenyl series" of acetophenone azines, (MeO-Ph, Y)-azines is successfully described. The methoxyphenyl chromophore offers significantly improved nonlinear optical (NLO) performance compared to the methoxy and phenoxy series (Paper IV).Furthermore, a series of 1-(4'-halophenyl)-4-(4"-methoxyphenyl)buta-1,3-dienes with halogens was synthesized. (MeO, Y)-butadienes exhibit much higher first-order molecular hyperpolarizabilities than their analogous (MeO, Y)-azines due to their higher dipole moments and larger conjugation lengths (Paper V).
546 $a English
590 $a School code: 0587
650 4 $a Chemistry. $3 516420
650 4 $a Physical chemistry. $3 1981412
650 4 $a Electrical engineering. $3 649834
653 $a Dipole moments
653 $a Idioteloamphiphile monolayers
653 $a Hyperpolarizabilities
690 $a 0485
690 $a 0544
690 $a 0494
710 2 $a Missouri University of Science and Technology. $b Chemistry. $e degree granting institution. $3 3823457
720 1 $a Glaser, Rainer $e degree supervisor.
773 0 $t Dissertations Abstracts International $g 86-03B.
790 $a 0587
791 $a Ph.D.
792 $a 2024
856 4 0 $u https://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=31487235