東華大學圖書館 |

Language: English

Help

回圖書館首頁

手機版館藏查詢

Back to Search results for [ null ]

Switch To: Labeled | MARC Mode | ISBD

Linked to FindBook

Google Book

Amazon

博客來

Improving the Accuracy of Mid-Infrared Determination of Fat, Protein, Lactose, and Urea in Milk.

Record Type:	Electronic resources : Monograph/item
Title/Author:	Improving the Accuracy of Mid-Infrared Determination of Fat, Protein, Lactose, and Urea in Milk./
Author:	Portnoy, Matilde.
Description:	1 online resource (184 pages)
Notes:	Source: Dissertations Abstracts International, Volume: 84-12, Section: B.
Contained By:	Dissertations Abstracts International84-12B.
Subject:	Food science. -
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=30249712click for full text (PQDT)
ISBN:	9798379722852

Improving the Accuracy of Mid-Infrared Determination of Fat, Protein, Lactose, and Urea in Milk.
Portnoy, Matilde.

Improving the Accuracy of Mid-Infrared Determination of Fat, Protein, Lactose, and Urea in Milk. - 1 online resource (184 pages)

Source: Dissertations Abstracts International, Volume: 84-12, Section: B.

Thesis (Ph.D.)--Cornell University, 2023.

Includes bibliographical references

Mid-infrared (MIR) instruments for milk analysis are used throughout the dairy industry for payment testing, herd management, and product manufacturing, as they provide a rapid/reliable method for measuring milk components. Milk MIR analysis is a secondary method requiring statistical prediction models and calibration for each measured component. Two prediction model approaches exist for measuring milk components from milk MIR spectra: basic filter models with intercorrection factors (IF) (for major milk components) and partial least squares (PLS) models (for major and minor milk components). Fat, protein, and lactose can be measured by basic filter models, while milk urea nitrogen (MUN), a metric of interest in herd management, is measured by PLS models. The current method for determination of IF (instrument-specific coefficients in basic filter models that account for background component variation) lacks robustness. Additionally, current MUN PLS models are often influenced by background matrix components, and, to achieve a complete system for MUN MIR measurement, a chemical reference method (for reference MUN values for calibration) with interlaboratory results approved by the Association of Official Analytical Chemists (AOAC) is needed. Therefore, this thesis had the following objectives: (i) develop a method to determine/optimize IF for MIR basic filter models using modified milk samples; (ii) conduct a collaborative study for AOAC-approval of an enzymatic/spectrophotometric reference method for MUN; and (iii) develop an improved PLS model for MUN MIR measurement. For objective (i), a multiple linear regression model followed by optimization was developed to calculate IF. IF were determined for nine MIR instruments and resulted with smaller magnitudes and lower variability among instruments than those reported previously using the traditional method. For objective (ii), a collaborative study was conducted with 10 laboratories and the enzymatic/spectrophotometric method for MUN showed improved repeatability and reproducibility (RSDR<1%) compared to other reported methods for milk urea. Finally, for objective (iii), a PLS model for MUN was developed using a variety of farm milks, individual-cow milks, and modified milks to train the model. The developed model showed good prediction accuracy at a wide range of MUN concentrations during cross-validation (RPD=5.3). External model validation is now required as the next step for implementation of the new PLS model in the industry.

Electronic reproduction.
Ann Arbor, Mich. :
ProQuest,
2023

Mode of access: World Wide Web

ISBN: 9798379722852Subjects--Topical Terms:

3173303
Food science.
Subjects--Index Terms:

Collaborative studyIndex Terms--Genre/Form:

542853
Electronic books.

Improving the Accuracy of Mid-Infrared Determination of Fat, Protein, Lactose, and Urea in Milk.
LDR:03981nmm a2200409K 4500 001 2363487
005 20231127093417.5
006 m o d
007 cr mn ---uuuuu
008 241011s2023 xx obm 000 0 eng d
020 $a 9798379722852
035 $a (MiAaPQ)AAI30249712
035 $a AAI30249712
040 $a MiAaPQ $b eng $c MiAaPQ $d NTU
100 1 $a Portnoy, Matilde. $3 3704249
245 1 0 $a Improving the Accuracy of Mid-Infrared Determination of Fat, Protein, Lactose, and Urea in Milk.
264 0 $c 2023
300 $a 1 online resource (184 pages)
336 $a text $b txt $2 rdacontent
337 $a computer $b c $2 rdamedia
338 $a online resource $b cr $2 rdacarrier
500 $a Source: Dissertations Abstracts International, Volume: 84-12, Section: B.
500 $a Advisor: Barbano, David M.
502 $a Thesis (Ph.D.)--Cornell University, 2023.
504 $a Includes bibliographical references
520 $a Mid-infrared (MIR) instruments for milk analysis are used throughout the dairy industry for payment testing, herd management, and product manufacturing, as they provide a rapid/reliable method for measuring milk components. Milk MIR analysis is a secondary method requiring statistical prediction models and calibration for each measured component. Two prediction model approaches exist for measuring milk components from milk MIR spectra: basic filter models with intercorrection factors (IF) (for major milk components) and partial least squares (PLS) models (for major and minor milk components). Fat, protein, and lactose can be measured by basic filter models, while milk urea nitrogen (MUN), a metric of interest in herd management, is measured by PLS models. The current method for determination of IF (instrument-specific coefficients in basic filter models that account for background component variation) lacks robustness. Additionally, current MUN PLS models are often influenced by background matrix components, and, to achieve a complete system for MUN MIR measurement, a chemical reference method (for reference MUN values for calibration) with interlaboratory results approved by the Association of Official Analytical Chemists (AOAC) is needed. Therefore, this thesis had the following objectives: (i) develop a method to determine/optimize IF for MIR basic filter models using modified milk samples; (ii) conduct a collaborative study for AOAC-approval of an enzymatic/spectrophotometric reference method for MUN; and (iii) develop an improved PLS model for MUN MIR measurement. For objective (i), a multiple linear regression model followed by optimization was developed to calculate IF. IF were determined for nine MIR instruments and resulted with smaller magnitudes and lower variability among instruments than those reported previously using the traditional method. For objective (ii), a collaborative study was conducted with 10 laboratories and the enzymatic/spectrophotometric method for MUN showed improved repeatability and reproducibility (RSDR<1%) compared to other reported methods for milk urea. Finally, for objective (iii), a PLS model for MUN was developed using a variety of farm milks, individual-cow milks, and modified milks to train the model. The developed model showed good prediction accuracy at a wide range of MUN concentrations during cross-validation (RPD=5.3). External model validation is now required as the next step for implementation of the new PLS model in the industry.
533 $a Electronic reproduction. $b Ann Arbor, Mich. : $c ProQuest, $d 2023
538 $a Mode of access: World Wide Web
650 4 $a Food science. $3 3173303
650 4 $a Analytical chemistry. $3 3168300
650 4 $a Animal sciences. $3 3174829
653 $a Collaborative study
653 $a Mid-infrared instruments
653 $a Milk urea nitrogen
653 $a PLS models
653 $a Association of Official Analytical Chemists
653 $a Milk components
655 7 $a Electronic books. $2 lcsh $3 542853
690 $a 0359
690 $a 0486
690 $a 0475
710 2 $a ProQuest Information and Learning Co. $3 783688
710 2 $a Cornell University. $b Food Science and Technology. $3 3546528
773 0 $t Dissertations Abstracts International $g 84-12B.
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=30249712 $z click for full text (PQDT)