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Evaluation and Development of Weakly Coordinating Cations and Their Application to Charge-Enhanced Base Organocatalysis.

Record Type:	Electronic resources : Monograph/item
Title/Author:	Evaluation and Development of Weakly Coordinating Cations and Their Application to Charge-Enhanced Base Organocatalysis./
Author:	Dempsey, Stephen H.
Description:	1 online resource (693 pages)
Notes:	Source: Dissertations Abstracts International, Volume: 84-09, Section: B.
Contained By:	Dissertations Abstracts International84-09B.
Subject:	Organic chemistry. -
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=30310156click for full text (PQDT)
ISBN:	9798377644545

Evaluation and Development of Weakly Coordinating Cations and Their Application to Charge-Enhanced Base Organocatalysis.
Dempsey, Stephen H.

Evaluation and Development of Weakly Coordinating Cations and Their Application to Charge-Enhanced Base Organocatalysis. - 1 online resource (693 pages)

Source: Dissertations Abstracts International, Volume: 84-09, Section: B.

Thesis (Ph.D.)--University of Minnesota, 2023.

Includes bibliographical references

Reactive ions are ubiquitous species in diverse areas of chemistry. Numerous studies have shown that cations paired with weakly coordinating anions can lead to potent and unexpected reactivity. In contrast, relatively little has been done with weakly coordinating cations paired with reactive anions. In the first part of this dissertation, current literature-standard weakly coordinating cations are examined and the synthesis and evaluation of new phosphonium cations is presented.Organocatalysis is a powerful component of the modern synthetic chemist's toolbox. Previous work in the Kass group has shown that the inclusion of a positive charge onto acidic organocatalyst motifs leads to potent reactivity enhancements. The latter half of this dissertation discusses the inverse, where an anionic center was included on a basic pyridine moiety and the resulting electrostatically enhanced base organocatalysts reactivity was examined. Additionally, an exploration of the ionic structure of the most potent catalysts via a variety of methods is presented.

Electronic reproduction.
Ann Arbor, Mich. :
ProQuest,
2023

Mode of access: World Wide Web

ISBN: 9798377644545Subjects--Topical Terms:

523952
Organic chemistry.
Subjects--Index Terms:

Reactive ionsIndex Terms--Genre/Form:

542853
Electronic books.

Evaluation and Development of Weakly Coordinating Cations and Their Application to Charge-Enhanced Base Organocatalysis.
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